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Updated Site Conceptual Model and Third Quarter 2002 Monitoring and Remediation Report <br /> Cleanup and Abatement Order No 5-00-707 EAI Prosect No 1232 <br /> 4.0 REMEDIATION SYSTEM STATUS REPORT <br /> Due to low concentrations of VOCs observed in the extracted soil vapor during the second <br /> quarter 2002 quarterly system testing, the oxidizer was operated only 88 hours during the third <br /> quarter 2002 However, the air spargnng compressor was operated for approximately 1300 <br /> hours alternatively for one week on the Wards site and then one week on the Unocal site The <br /> compressor operation was coordinated with the construction activities on the Ward site <br /> On September 28, 2002, the oxidizer was restarted to obtained VOC readings from individual <br /> vapor extraction wells using a PID All readings were near the detection limit with the <br /> exception of well VIEW-2 on Ward site which had a PID reading of 230 ppmv and well 25S on <br /> Unocal site which had a PID reading in excess of 1,000 ppmv <br /> On September 30, 2002, soil vapor samples were obtained from the inlet of the oxidizer while <br /> operating separately on Ward and Unocal sites The samples were analyzed for TPH-G, <br /> BTEX, and MTBE by EPA Methods 8015M and 802113, and for carbon dioxide, methane, and <br /> oxygen by ASTM-D 1946 <br /> The sample obtained from the Ward's wells contained a TPH-G concentration below the <br /> detection limit of 10 ppmv and benzene, toluene, and ethylbenzene below the detection limit of <br /> 0 1 ppmv, total xylenes of 0 37 ppmv, and MTBE below of detection limit of 0 5 ppmv The <br /> soil vapor contained 0 41% carbon dioxide which indicates that hydrocarbons in the subsurface <br /> are subjected to the biodegradation activity, and 19 90% oxygen which suggests aerobic <br /> conditions in the subsurface <br /> The sample obtained from the Unocal's wells contained TPH-G at 79 ppmv, benzene at 0 44 <br /> ppmv, toluene and ethylbenzene, total xylenes below the detection limit of 0 2, and MTBE at <br /> 3 1 ppmv (no confirmation testing by EPA Method 8260B was performed) The soil vapor <br /> contains 1 41% carbon dioxide which is three times higher than on Ward's site, and 19 70% <br /> oxygen <br /> The analytical data and chain of custody are presented in Appendix C <br /> As required by conditions of the air quality permit, quarterly sampling was performed on <br /> September 30, 2002 No analytes were detected above the detection limit (see Appendix C) <br /> Since starting the remedial system, the thermal oxidizer has operated for a total of 5,754 hours <br /> and the sparging compressor for 8,222 hours, removing approximately 8,454 pounds of <br /> petroleum hydrocarbons from impacted soil and ground water (see Tables 5 and 6) The <br /> amount of biodegraded hydrocarbons is not included in this total and is difficult to calculate <br /> BHM WORD t232Ro291 -7- ENVIRONMENTAL AUDIT, INC <br />