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v <br /> A S S O C I A T E S I N C <br /> • A hydraulic conductivity value of 0.0012 cm/s (4x10' feet per second) was selected. This <br /> value falls within the range of values that are typical of silty sands (Freeze and Cherry, <br /> 1979). Subsequent to the calibration of the flow model, the transport model was calibrated <br /> by adjusting the concentration of recharge flux until the longitudinal extents of the two sets <br /> of TPHg isocontours were in approximate agreement. Groundwater hydrocarbon <br /> concentrations predicted from the flow and transport model and those from laboratory <br /> analytical data collected during the groundwater monitoring events may not exhibit exact <br /> agreement. However, the model does appear to predict the general spread and extent of the <br /> hydrocarbon plume and the approximate hydrocarbon concentrations in the wells over time. <br /> • The mass balance calculations of hydrocarbons present in water beneath the site were <br /> calculated based on areas estimated from isocontours produced from November 2003 <br /> laboratory analytical data. Volumes were calculated by multiplying these areas by a depth of <br /> 15 feet. This calculation would appear to be a conservative estimation since the <br /> contaminants are primarily short carbon chain hydrocarbons that would tend to be <br /> concentrated near the water surface. However, there appears to be over 2,600 kilograms of <br /> hydrocarbons remaining in the soil beneath the site. The MODFLOW model utilized the <br /> recharge package to simulate the loading of the hydrocarbon plume due to leaching of <br /> hydrocarbons sorbed in the soil to groundwater. Additionally, the MTRCTI chemical <br /> reaction package was utilized in the MT3D transport model to simulate biodegradation of <br /> hydrocarbons and the interaction of aqueous-phase and solid-phase concentrations. <br /> Discussion of No Further Action Required Reporting Criteria <br /> • Criterion 3: Contaminants remaining in the vadose zone cannot migrate in soil vapor 01- <br /> leach at concentrations that would cause groundwater to exceed water quality objectives <br /> The EHD indicated that the soil model does not account for rising or falling groundwater <br /> elevation of for contaminant flux from submerged impacted soil. <br /> The model was roughly calibrated to field data while utilizing the MODFLOW recharge <br /> package and the MT313 chemical reaction package, therefore, the model does account for <br /> flux from vadose zone contaminant flux as well as submerged impacted soils. <br /> • Criterion 4: There are no existing water supply wells, sur face waters of other receptors <br /> threatened by the remaining contaminants in soil or groundwater. <br /> The EHD indicated that the main threat posed by the plume, should it expand under natural <br /> conditions, would be to additional volumes of groundwater currently not impacted by <br /> petroleum hydrocarbons. <br /> It is apparent from the groundwater receptor survey that the plume does not threaten water <br /> quality in any wells in the adjacent area. EHD's opinion that "the main threat posed by the <br /> plume, should it expand under natural conditions, would be to additional volumes of <br /> groundwater currently not impacted by petroleum hydrocarbons" extends criterion 4 beyond <br /> env ironmenta1127142\reponse.doc 3 <br />