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Mr. James L.L. Barton V <br /> January 5, 2004 <br /> Page 2 of 3 <br /> November 18, 2003: Ground Zero notified by laboratory that the sample collected from EFF on <br /> November 17, 2003 contained 9.2 ppb MTBE, but no other detectable VOCs. The sample <br /> collected from Cl contained 5,900 ppb MTBE, 780 ppb benzene, and 140 ppb toluene. The <br /> treatment system was shut down immediately upon notification of the results. The flow totalizer <br /> indicated that 21,685 gallons of water had been treated through the carbon units. <br /> November 21, 2003: Pump removed from extraction well and replaced by passive skimmer to <br /> remove measurable free product during period of nonoperation. <br /> December 1, 2003: Carbon replaced in both units. Supplemental 200-pound carbon unit <br /> plumbed in to treatment system after the lag 2,000-pound carbon unit. <br /> December 3,2003: Passive skimmer removed from extraction well and pump re-installed and <br /> tested. <br /> December 4, 2003: Virgin carbon wetted and system pressure tested. System failed pressure test <br /> and new gaskets ordered from Carbon Resources. <br /> December 10, 2003: Gaskets replaced in both carbon units and system passed pressure test. <br /> December 11, 2003: Regional Board and San Joaquin County (EHD) notified and system <br /> restarted, witnessed by Regional Board and EHD staff. Bi-weekly sampling program established <br /> pursuant to Regional Board requirement. <br /> January 2, 2004: Treatment system has operated continuously since December 11, 2003, <br /> treating approximately 47,929 gallons of water since carbon replaced. Results of C l, C2, EFF ND <br /> for VOCs, including MTBE, for samples collected on December 11, December 15, December 18, <br /> December 22, December 26, and December 30, 2003, as well as January 2, 2004. Tables 1 and 2, <br /> attached, summarize treatment system flow and analytical data collected to date. <br /> ANALYSIS OF BREAKTHROUGH <br /> In a follow up letter (October 28, 2003) to the Report of Waste Discharge submitted for the site, <br /> Ground Zero stated that carbon usage in the treatment system was estimated at between 37 and 63 <br /> pounds per day, depending upon the type of carbon used. At this rate the primary carbon vessel <br /> would initially require change out every 31-54 days, based upon then current analytical results from <br /> well MW 1 (28,000 ppb MTBE). The carbon usage estimates were provided by several contractors. <br /> Carbon usage estimates are attached. <br /> Breakthrough of the carbon units actually occurred after approximately 5 days, which is an order of <br /> magnitude quicker than estimated. Ground Zero attributes this accelerated breakthrough to two <br /> primary factors: <br /> 1. Initial testing and start up of the treatment system included testing of the pump placed in the <br /> extraction well. Excessive drawdown of the well during initial testing and calibration of the <br />