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Canepa s Car Wash <br /> 6230 Pacific Avenue,Stockton,CA <br /> First Quarter Groundwater Monitoring Report,January 2005 <br /> Page 4 of 8 <br /> . LABORATORY ANALYTICAL RESULTS <br /> Groundwater samples collected from the monitoring wells and SV4 were analyzed for total petroleum <br /> hydrocarbons quantified as gasoline (TPH-G) by EPA Method 8015M and benzene, toluene, ethyl <br /> benzene, and total xylenes (BTEX) and selected gasoline oxygenates/additives by EPA Method 8260B by <br /> Excelchem Environmental Labs of Roseville, California (Excelchem) The selected oxygenates/additives <br /> included MTBE, ethanol (EtOH), tertiary-butanol (TBA), dl-isopropyl ether (DIPE), ethyl tert-butyl ether <br /> (ETBE), tert-amyl methyl ether(TAME), 1,2-dichloroethane (1,2-DCA), and 1,2-dibromoethane (EDB) <br /> The current groundwater sample analytical results (Table 3, below) are generally consistent with the <br /> historic results with the exception of MW-1 (Table A, Attachment C) None of the contaminants of <br /> concern were detected at or above the laboratory reported detection limits in monitoring wells MW-4, <br /> MW-9, and MW-12D <br /> The laboratory analytical results of the sample collected from MW-3 indicate that the MTBE <br /> concentration decreased relative to the October 2004 sample (Figure 6, Attachment A) Contaminant <br /> concentrations in the sample collected from MW-1 increased significantly relative to the July 2004 <br /> monitoring event and are generally at the highest concentrations since June 1995 This increase is <br /> anticipated as the groundwater extraction draws the center of the contaminant plume toward it Benzene <br /> and MTBE iso-concentration contour maps are included as Figures 4 and 5, respectively, Attachment A <br /> Laboratory certificates of analyses and chain of custody records are included in Attachment F <br /> Table 3 <br /> Groundwater Sample Laboratory Analytical Results (January 21 and 24, 2005) <br /> Constituent Benzene Toluene Ethyl Total TPH-G MTBE Other Gasoline <br /> Benzene Xylenes <br /> MCL 1 pg/L 150 pg/L 700 pg/L 1 750 pg/L 13 pg/L Oxygenates/Additives <br /> Analytical Method—+ 8260B 8260B 8260B 8260B 8015m 8260B 8260E <br /> Reporting Limits--+ 0 5 gulf- 0 5 pg/L 0 5 gg/L 1 0 pg/L 005 05 05-20 <br /> Sample I D mg/L pg/L p� <br /> 1707-MWI-1121105 8,400 3,800 13 3,280 30 7,200 < 1 0-<40 <br /> 1707-MW2-1/21/05 8,300 1,100 2,500 4,370 37 <1 0 < 1 0-<40 <br /> 1707-MW3-1121105 13 <1 0 <10 <3 0 0 54* 1,500 82(1,2-DCA) <br /> 1707-MW4-1/21/05 <0 5 <0 5 <0 5 <1 5 <0 05 <0 5 <0 5 -<20 <br /> 1707-MW9-1/21/05 <0 5 <0 5 <0 5 <1 5 <0 05 <0 5 <0 5 -<20 <br /> 1707-MW 11-1/21/05 320 84 2 4 173 0 78* 550 <0 5-<20 <br /> 1707-MW 12D-1/21105 <0 5 <0 5 <0 5 <1 5 <0 OS <0 5 <0 5-<20 <br /> <5vv-<2v,unn <br /> 32 <br /> 1707D-SVE4-1/24105 77,000 68,000 4,900 24,000 360 0,000 <br /> VU <br /> Bold analytical data exceed California MCL(Maximum Contaminant Level) <br /> *= Me sample chromatogram does not match the standard gasoline chromatogram <br /> Units Analytical <br /> mg/L=milligrams per liter=parts per milhon(ppm) B T E X=benzene toluene,ethyl benzene,total xylenes <br /> pg/L=micrograms per liter=parts per billion(ppb) TPH-G=total petroleum hydrocarbons quantified as gasoline <br /> Gasoline oxygenates/additives= methyl tertiary-butyl ether(MTBE),ethanol, <br /> • tertiary-butanol (TBA), di-isopropyl ether (RIPE), ethyl tertiary butyl ether <br /> (ETBE), tertiary-amyl methyl ether (TAME) 1,2-drehloroethane (1,2-RCA), <br /> 1,2-dibromoethane(1,2-EDB) <br /> �� CONDOR <br />