Laserfiche WebLink
Measurements of dissolved oxygen in groundwater samples collected from site wells in <br /> February 1999 provide the basis to conclude that aerobic biodegradation is also acting to <br /> attenuate the petroleum hydrocarbons present in site soil and groundwater. Concentrations of <br /> dissolved oxygen in groundwater from wells MW-1, MW-2, MW-3, and MW-6 (the four shallow <br /> wells that have historically defined the core of the site's groundwater plume) were less than <br /> 0.5 ppm. Concentrations of dissolved oxygen in groundwater from up-gradient, cross-gradient, <br /> and down-gradient monitor wells ranged from 2.24 to 5.49 ppm. Thus the low dissolved oxygen <br /> concentration associated with the Iocation of the release relative to the higher concentrations at <br /> distance further demonstrates the on-going biodegradation and attenuation of the hydrocarbon <br /> plume. <br /> In considering possible impacts to current and future beneficial uses of groundwater, <br /> three factors are relevant: 1) according to Department of Water Resources (D WR) Bulletin <br /> 146 (1967) and Petitioner's March 1998 sample analyses, shallow groundwater in the vicinity of <br /> the site is of"inferior quality," 2) the groundwaters monitored by site wells are not in direct <br /> hydraulic communication with deeper groundwater aquifers or local supply wells, and 3) as <br /> discussed above, the plume is stable and concentrations are decreasing as a consequence of <br /> natural attenuation. The presence of poor quality water(which generally contains elevated <br /> concentrations of nitrate, chloride, and TDS) in the Victor Formation is a consequence of the <br /> easterly intrusion of poor quality water underlying the Delta and the Stockton Deep Water Ship <br /> Channel over the past 50 years or so. An analysis of water level elevation data for site wells also <br /> shows an absence of the seasonal fluctuations one would expect if the groundwater monitored <br /> was in direct hydraulic communication with local production wells. Hence, the localized volume <br /> of affected water is not currently being used and, due to its inferior quality, is not likely to be <br /> used in the future. Furthermore, historic groundwater monitoring data, in addition to showing <br /> plume stability and decreasing constituent concentrations, shows that the poor quality of the <br /> shallow groundwater enhances the on-going bioremediation, consequently reducing the residual <br /> petroleum hydrocarbon mass in the subsurface. Because constituent concentrations will continue <br /> to decline as the mass of residual petroleum hydrocarbons decrease over time, continued <br /> monitoring of site groundwater would serve no useful purpose. <br /> The only way to ensure complete removal of lingering, residual, detectable <br /> concentrations of petroleum constituents in site groundwater would be to excavate an additional <br /> several thousand cubic yards of affected soil to depths in excess of 50 feet. This would entail a <br /> 11 <br />