Laserfiche WebLink
It <br /> 1 <br /> ATTACHMENT 1 <br /> Revised Estimate of Hydrocarbons Remaining in Soil <br /> The revised mass of hydrocarbons remaining in soil was estimated to be 11.5 pounds. The <br /> remaining mass is confined within a 4,550 square foot area measuring 5 feet thick which extends <br /> northeast beyond the overexcavation limits. The revised residual hydrocarbon mass estimate was <br /> based on the following assumptions: <br /> - All hydrocarbons remaining in soil are located downgradient from the northeast limits of the <br /> overexcavation. <br /> -The areal extent of hydrocarbons remaining in soil is confined between the downgradient limits <br /> of the overexcavation and the downgradient extent of the former dissolved hydrocarbon plume <br /> (Attachment 2). <br /> -The vertical extent of hydrocarbons is confined between 31.0 and 36.0 feet below surface. These <br /> confining depths are based on the shallowest residual contamination measured at 31.0 feet in <br /> sample TX-27 and the vertical extent of contamination defined at 36.0 feet by overexcavation <br /> sample TB-8. <br /> - 6.0 ppm TPHG (measured at sample TX-26) was applied uniformly throughout the estimated <br /> soil volume as the representative residual hydrocarbon concentration. <br /> -A bulk density value of 1.35 glcc was used to represent the confined soil volume. This is a <br /> published mean value described to be representative of all soil types. <br /> -The actual calculations used to derive this revised mass estimate are provided in Attachment 3. <br /> It should be pointed out that the revised mass estimate is conservatively high. The TPHG <br /> concentration which was uniformly applied throughout the revised bulk soil volume is probably <br /> greater than actual. The residual hydrocarbon detected in soil at TX-26 is thought to represent the <br /> downgradient extent of a formerly migrating groundwater plume. Therefore, any residual <br /> hydrocarbon concentrations beneath and downgradient from this location would be lower due to <br /> natural attenuating factors. Support for this was demonstrated by non-detect levels of TPHG <br /> measured during the destruction of well MW-6. Additionally, the revised contaminated soil volume <br /> is probably greater than actual. The revised areal extent was increased to account for the detection <br /> of trace levels of xylenes at well MW-8 and to account for the possibility that TPHG remains at <br /> concentrations lower than 10 ppm (former detection limit) in soil within the area of the former <br /> dissolved hydrocarbon plume. <br /> The percent of benzene estimated to be remaining within the revised contaminated soil volume is <br /> zero. This estimate was based on the fact that benzene has never been detected in soil samples <br /> downgradient from the overexcavation limits. This is easily explained by the fact that benzene <br /> biodegrades more rapidly than other BTEX constituents and by the fact that it volatilizes more <br /> readily. <br /> Considering the revised mass estimate and the composition of the remaining hydrocarbons, <br /> Chevron still maintains there is no significant threat to groundwater remaining at this site. <br />