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-- - --- --No 316 B1~N7F_NE-- 4'9f, - --- ----- - ---- - ---- -- - -- --- - -- - --� - ----- - -----� —� -
<br /> SECTION ( IiEkLTlf HAZARD INF()itMATION
<br /> Benzene is listed as a suspected human carcinogen by the ACG1H
<br /> Summar} of Risks Prolonged shin contact with benzene or excessive inhalation of its rt apor mi% cause headache,weakness,loss of
<br /> appetite,and lassitude Continued exposure can cause collapse,bronchitis,and pneumonia The most important health hazards are cancer
<br /> (leukemia), bone marrow effects, and injuries to the blood-forming tissue from chronic low-level exposure
<br /> Medical Conditions _Aebravated by Long-Term Exposure Ailments of the heart, lungs,liver,kidneys,blood,and central
<br /> nervous system(CNS)ma) be worsened b)'exposure"Adrruniste-r preplacement and periodic medical exams emphasizing these organs'
<br /> functions and reassign Aorkers who test positive Target Organs Blood,CNS,bone marrow,eyes,and upper respiratory tract
<br /> (URT) Primary Entr} Skin contact, inhalation Acute Effects Dizziness,mental dullness,nausea,headache,fatigue,and
<br /> _ giddiness Chronic Effects Possible cancer(leukemia)
<br /> FIRST AID
<br /> Eyes Immediately flush eyes,including under the eyelids, genii),but thoroughly w ith plenty of running water for at least 15 minutes
<br /> Skln Immediately wash the affected area with soap and water
<br /> Inhalation Remove the exposed person to fresh air,restore andior support his or her breathing as needed
<br /> Ingestion Never give anything by mouth to someone who is unconscious or convulsing Do not induce vomiting because of the
<br /> -possibility of aspiration -
<br /> GET MEDICAL HELP (IN PLANT, PARAMrDIC, COMMUNITY) FOR ALL EXPOSURES Seek prompt
<br /> medical assistance for further treatment, obseriation, and support after first aid
<br /> SECTION 7 SPILL, LEAK, AND DISPOSAL PROCEDURES
<br /> Spill/Leak Notify safety personnel,provide ventilation,and eliminate all sources of ignition immediately Cleanup personnel need
<br /> Protection against contact with and inhalation of vapor(see sect.8) Contain large spills and collect waste or absorb it with an inert material
<br /> such as sand,earth,or vermiculite Use nonsparking tools to place waste liquid or absorbent into closable containers for disposal Keep
<br /> waste out of sewers,watersheds,and waterways
<br /> W aste_D isposal -Contact your supplier or a licensed contractor for detailed recommendations for disposal Follow Federal, state,and --
<br /> local regulations -
<br /> OSHA Designations
<br /> Air Contaminant(29 CFR 19 10 1000 Subpart Z)
<br /> EPA Designations (40 CFR 302 4)
<br /> RCRA Hazardous Waste,No U019
<br /> CERCLA Hazardous Substance,Reportable Quantity 1000 lbs(454 kg)
<br /> SECTION S. SPECIAL PROTECTION INFORMATION
<br /> Goggles Alkays wear protective eyeglasses or chemical safes) goggles Where splashing is possible,wear a full face shield Follow the
<br /> eye-and face-protection guidelines in 29 CFR 1910 133 Respirator Wear a NIOSH-approved respirator per the NIOSH Pocker Guide
<br /> to Chemical Hazards for the maximum-use concentrations and/or the exposure hnvts cited in section 2 Follow the respirator guidelines in
<br /> 29 CFR I910 134 For emergency or nonroutine use(c g,cleaning reactor s essels or storage tanks),wear an SOBA with a full facepiece
<br /> _ _Gperated in the pressure-demand or positive-pres sure mode `arnins _Air-purifying respirators will not protectworkers in oxygen,
<br /> deficient atmospheres Other Wear impervious gloves,boots,aprons,gauntlets,etc,to prevent any possibility of skin contact with this
<br /> suspected human carcinogen N entilanon__Install_and operate general and local ventilations ystems powerful enough to maintain__
<br /> aubome levels of benzene below the OSHA PEL standard cited in section 2W - _— _ _
<br /> Safety Stations Make eyewash stations,washing facilities, and safety showers available in use and handling areas = Contaminated
<br /> Equipment Contact lenses pose a special hazard,soft lenses may absorb irritants and all lenses concentrate them Donor wear contact
<br /> lenses in any work area Remove contaminated clothing and launder it before wearing it again,clean this material from shoes and
<br /> equipment. Comments Practice good personal h)gicne,always wash thoroughly after using this material Keep it off of your clothing
<br /> and equipment Avoid transferring it from your hands to your mouth while eating,drinking, or smoking Do nor eat,drink,or smoke ih
<br /> any work area Do not inhale benzene vapor'
<br /> SECTION 9 SPECIAL PRECAUTIONS AND COMMENTS
<br /> Storage/Segregation Storz:benzene in a cool,dry,well-ventilated area away from sources of ignition and incompatible chemicals
<br /> Special Handl ins/Storage Protect containers from physical damage Electrically ground and bond all metal containers used in
<br /> shipping or transfemng operations Follow all parts of 29 CFR I910 1028
<br /> Engineering Controls All engineering systems(production,transportation,etc)must be of maximum explosion-proof design(non-
<br /> sparking,electncally grounded and bonded,etc)
<br /> Comments If possible,substitute less toxic solvents for benzene,use this material with extreme caution and only if it is absolutely
<br /> essential
<br /> Transportation Data (49 CFR 172 101-2)
<br /> DOT Shipping Name Benzene AOT Label Flammable Liquid INIO Label Flammable Liquid
<br /> DOT Class Flammable Liquid DOT ID No UN1114 Ih40 Class 32
<br /> References 1,2. 12,73,84-94, 100, 103
<br /> ludgmemss as to the suitatiday of mfom%auon herein for purchasers purposes are ! prepared by PJ Igoe, BS
<br /> necessarily purchaser s responsibility Therefore a+though reasonable care has € -
<br /> been taken to the preparation of such information Gemum Pub)shtng Corp Indu5tt71al Hygiene Review DJ WIISOR,CIH
<br /> extends no wamaues,makes no representations and assumes no responsibility
<br /> as to the accuracy or suitability of such information for appheation to i
<br /> purchasers intended purposes or for consequences of its use „t Medical Review MJ Hardies,MD
<br /> QpMglu C 19BB Gemwn Publ tshtng DsWrsttam
<br /> Anv en^ "cie uir nr re,Muct—wt,hmt tir r hh"A t, ,r nhih trd
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