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No 317 4186 TOLUENE
<br /> SECTION 6 HEALTH HAZARD INFORMATION JTLV _
<br /> 1 oluene is not consiacrea a carcinogen by Itis C., or A i apors o1 toluene may cause
<br /> irritation of the eyes, nose, upper respiratory tract, and skin Exposure to 200 ppm for 8 hours causes mild fatigue,
<br /> weakness, confusion, lacrunaL,on (tearing) and paresthesia (a sensation of pnekling, tingling, or creeping on the stun that
<br /> has no objecu%c cause) Exposure to higher concentrations may cause headache, nausea, dnzzrriess, dilated pupils, and
<br /> euphona, and, in seven; cases, may cause unconsciousness and death The liquid is irritating to the eyes and skin Contact
<br /> with the eyes may cause transient corneal damage, conjunctival irritation, and bums if not promptly removed Repeated
<br /> and/or prolonged contact with the skin may cause drying and cracking It may be absorbed through the skin to toxic
<br /> amounts Ingestion causes nrratatnon of the gastrointestinal tract and may cause effects resembling those from inhalation of
<br /> the vapor Chronic overexposure to toluene may cause reversible kidney and laver injury FIRST AID EYE COMAC 1'
<br /> Immediately flush eyes, including under eyelids, with running water for at least 15 minutes Get medical attention if irritation
<br /> persists * SKIN CONTACT Immediately flush skim (for at least 15 minutes) while removing contatxunated shoes and
<br /> clothing Wash exposed area with soap and water Get medical attention if irritation persists or if a largeyarea has been
<br /> exposed * INHALATION Remove victim to fresh air Restore and/or support breathing as required Keep victim warn and
<br /> quiet. Get medical help* INGESDON Give victim 1 to 2 glasses of water or milk Contact a poison control center Do not
<br /> induce vormung unless directed to do so Transpo-i victim to a medical factlnty Never give anything by mouth to a person
<br /> who is unconscious or convulsing * GET MEDICAL ASSISTANCE= In plant, paramedic, community Get medical help
<br /> for further treatment, observation, and support after first and, if indicated
<br /> SECTION 7. SPILL, LEAK, AND DISPOSAL PROCEDURES
<br /> SPI 1,11-FAK Notify safety personnel of large spills or leaks Remove all sources of heat and ignition Provide maximum
<br /> explosion-proof ventilation Limit access to spill arca to necessary personnel only Remove leaking containers to safe
<br /> _place if feasible_ Cleanup personnel need protection against contact with liquid and inhalation of vapor(see_ sect. 8) ___
<br /> WASTE DISPOSAL Absorb small spills with paper towel or venrnctiirie Contain large spills and collect if feasible, or -
<br /> absorb with vermiculite or sand Place waste solvent or absorbent into closed containers for disposal using nonsparkmg
<br /> tools Liquid can be flushed with water to an open holding area for handling Do not flush to sewer, watershed, or waterway
<br /> COMMENTS Place in suitable contamer for disposal oy a licensed contractor or burn in an approved incinerator Consider
<br /> reclaiming by distillation Contaminated absorbent can be buned in a sanitary landfill Follow all Federal, state, and local
<br /> regulations TLm 96 100-10 ppm. Toluene is designated as a hazardous waste by the EPA The EPA (RCRA) HW No is
<br /> U220 (40 CFR 261) The reportable quantity(RQ) is 1000 lbs/454 kg (40 CFR 117)
<br /> SECTIONS. SPECIAL PROTECTION INFORMATION
<br /> Provide general and local exhaust ventilation to meet TLV requirements Ventilation fans and other electrical service rrust be
<br /> nonsparkmg and have an explosion-proof design Exhaust hoods should have a face velocity of at least 100 lfm(lmedr feet
<br /> per minute) and be designed to capture heavy vapor For emergency or nonroutine exposures where the TLV may be exceeded,
<br /> ___use an organic ghgmical_cartndge respirator„if concentration-is less than 200 ppm and an_approved canister gas mask or self-_
<br /> contained breathing apparatus with full facepiece if concentration is greater than 200 ppm.
<br /> Safety glasses or splash goggles should be worn in all work areas Neoprene gloves, apron,face shield, boots, and other
<br /> appropnate protective clothing and equipment should be available and wom as necessary Io prevent-skin and eye cortico
<br /> Remove contaminated clothing immediately and do not wear it until it has been properly laundered
<br /> Eyewash stations and safety showers should be readily available in use and handling arras
<br /> Contact lenses pose a special hazard, soh lenses may absorb irritants and all lenses concentrate them.
<br /> SECTION 9. SPECIAL PRECAUTIONS AND COMMENTS
<br /> R GA E SF.G,UGATION Store in a cool, dry, well-ventilated area away from oxidizing agents, heat, sparks, or open flame
<br /> Storage areas must meet OSHA requirements for class IB flammable liquids Use metal safety cans for handling small amounts
<br /> Protect containers from physical damage Use only with adequate ventilation Avoid contact with eyes, skin, or clothing Do
<br /> not inhale or ingest Use caution when handling this compound because it can be absorbed through intact skin>m toxic
<br /> arnounts SPECIAL HANDLING/STORAGE Ground and bond metal containers and equipment to prevent static sparks when
<br /> making transfers Do not smoke in use or storage areas Use nonsparkmg tools ENGINEERING CON7-RQ S Preplacement
<br /> and penodic medical exams emphasizing the liver, kidneys, nervous system, lungs, hea.1, and blood should be provided
<br /> Workers exposed to concentrations greater than the action level (50 ppm) should be examined at least once a year Use of
<br /> alcohol can aggravate the toxic effects of toluene
<br /> COMMENTS Emptied contamers contain product residues Handle accordmglyl
<br /> Toluene is designated as a hazardous substance by the EPA (40 CFR 116) DOT Classification Flammable liquid UN1294
<br /> Data Source(s) Code 1-9, 12, 16, 20, 21,24,26, 34 81, 82 CR
<br /> ]udgemears as to the suitability of informsoon herein for purchase's purpos% Appi-m al_S Bo f�GaRoGra, f!/y(s .
<br /> are necemanly psrchws&a rrsponsibili t Therefore,although reasonable rare
<br /> has been taken in the prrpWzt;on of lush mformirion Gemum Pubbslunp Corp indust H tenelSafets p/
<br /> extends no warranties makes no reprrsent=rons and waumes no responsib It",as Hygiene/Safety
<br /> ty
<br /> LO the accuracy or auitabbty of such mformauoo for applrciuon to purchases
<br /> intended purposes or rorcou"umces of rte use. Medical Revievi
<br /> hiO1986Ce =Pubtis w.
<br /> A. u�,zw e:reproduetam t pwmri,�r,permstim n prohm�ted Copynght 0 April 1, 1986
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