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MSDS 8 <br /> July 1,2002 <br /> XYLENE properly. If material does not contain or is not mixed with an <br /> Increased susceptibility to the ffects of this material may be isocyanate activator/hardener:Wear a properly fitted air-purifying <br /> observed in people with preexisting disease of any of the following: respirator with organic vapor cartridges(NIOSH approved TC-23C), <br /> bone marrow cardiovascular system central nervous system eye protection,gloves and protective clothing. Confine, remove with <br /> kidneys liver lungs inert absorbent,and dispose of properly. <br /> Can be absorbed through the skn in harmful amounts. <br /> Can irritate or bum eyes. Rea ent overexposure may result in liver SECTION 7-Handling and Storage <br /> and kidney injury.High exposur s may produce irregular heartbeats. <br /> Canada classifies Xylene as a de elopmental toxin as high exposures Precautions to be taken in handling and storing: <br /> to xylenes in some animal stud* have been reported to cause health Observe label precautions.If combustible(flashpoint between 100- <br /> effects on the developing fetus/ mbryo.These effects were often at 2001F), keep away from heat,sparks and flame.If flammable <br /> levels toxic to the adult animal. e significance of these effects (flashpoint less than 100°F),also keep away from static <br /> to humans is not known. Asp on may occur during swallowing or discharges and other sources of ignition.If material is extremely <br /> vomiting,resulting in lung dama e.Material may be harmful or fatal if flammable(flashpoint less than 20°F)or flammable,VAPORS MAY <br /> swallowed. Prolonged or repeat d skin contact may cause drying, IGNITE EXPLOSIVELY OR CAUSE FLASH FIRE,respectively.Vapors <br /> cracking,or irritation. may spread long distances.Prevent buildup of vapors.Close container <br /> after each use.Ground containers when pouring.Wash thoroughly <br /> SECTION 4-First Aid Measures after handling and before eating or smoking.Do not store above <br /> 120°F.If product is waterbased,do not freeze. <br /> First Aid Procedures: Other precautions: <br /> Inhalation: If material is a coating:do not sand,flame cut,braze or weld dry <br /> If affected by inhalation of vapor6r spray mist,move to fresh air. coating without a NIOSH approved respirator or appropriate <br /> If not breathing,give artificial re iration,preferably ventilation,and gloves. <br /> mouth-to-mouth. If breathing di culty persists,or occurs later, <br /> consult a physician. SECTION 8-Exposure Controls or Personal Protection <br /> Ingestion: <br /> In the unlikely event of ingestion,DO NOT INDUCE VOMITING. Call Engineering controls and work practices: <br /> a physician immediately and have names of ingredients available. Ventilation: <br /> Skin or eye: Provide sufficient ventilation in volume and pattern to keep <br /> In case of eye contact, immediat y flush with plenty of water for at contaminants below applicable exposure limits. <br /> least 15 minutes;call a physician.In case of skin contact,wash Respiratory: <br /> thoroughly with soap and water.I�irritation occurs,contact a Do not breathe vapors or mists. If this product contains <br /> physician. isocyanates or is used with an isocyanate activator/hardener,wear a <br /> positive-pressure,supplied-air respirator(NIOSH approved TC-19C) <br /> SECTION 5-Firefigh 'ng Measures while mixing activator/hardener with paint,during application and <br /> until all vapors and spray mist are exhausted. If product does not <br /> Flash Point(Closed Cup) See Section 1 for exact values. contain or is not mixed with an isocyanate activator/hardener,a <br /> Flammable limits LFL 0.0% FL 13.1% properly fitted air-purifying respirator with organic vapor <br /> Extinguishing media: cartridges(NIOSH TC-23C)and particulate filter(NIOSH TC-84A)may <br /> Universal aqueous film-forming fo m,carbon dioxide,dry chemical. be used. Follow respirator manufacturer s directions for respirator <br /> Fire fighting procedures: use.Do not permit anyone without protection in the painting area. <br /> Full protective equipment,includin self-contained breathing Individuals with history of lung or breathing problems or prior <br /> apparatus, is recommended.Wate from fog nozzles may be used to reaction to isocyanates should not use or be exposed vapor or spray <br /> prevent pressure build-up. mist if product contains or is mixed with isocyanate <br /> Fire&explosion hazards: activators/hardeners. <br /> For flammable liquids,vapor/air wi I ignite when an ignition source Protective dothing: <br /> is present. In other cases,when heated above the flash point,emits Neoprene gloves and coveralls are recommended. <br /> flammable vapors which,when mi ed with air,can burn or be Eye protection: <br /> explosive. Fine mists or sprays may be flammable at temperatures Desirable in all industrial situations.Goggles are preferred to <br /> below the flash point. prevent eye irritation. If safety glasses are substituted,include <br /> SECTION 6-Accidental R�lease Measures splash guard or side shields. <br /> Steps to be taken in case material is rel sed or spilled: SECTION 9-Physical and Chemical Properties <br /> Ventilate area. Remove sources of ignition.Prevent skin and eye Evaporation Rate Slower than Ether <br /> contact and breathing of vapor. If he material contains,or is mixed Solubility in water NIL <br /> with an isocyanate activator/harde er:Wear a positive-pressure, Vapor Density Heavier than air <br /> supplied-air respirator(NIOSH appr ved TC-19C),eye protection, Approx. boiling range(°C) No Data Available <br /> gloves and protective clothing. Poi liquid decontamination solution Approx.freezing range(°C) -92--93-(C) <br /> decontamination solutions for isocyate containing materials are: Specific gravity 0.97- 0.99over the spill and allow to sit at lea10 minutes. Typical Gallon weight(lbs./gal) 8.06- 8.29 <br /> 20%Surfactant (Tergitol TMN 10) d 80%Water OR 0-10% Percent volatile by volume 65.29- 76.58 <br /> Ammonia,2-5%Detergent and War(balance) Pressure can be Percent volatile by weight 58.75- 72.56 <br /> generated.Do not seal waste containers for 48 hours to allow C(z to Percent solids by volume 23.42- 34.71 <br /> vent. After 48 hours,material may rhe sealed and disposed of Percent solids by weight 27.44- 41.25 <br /> 3 <br /> MSDS 8 <br /> July*, 2002 <br /> © 2001-2002 E.I. du Pont de Nem uirs and Company.All rights reserved. Reproduction or translation of any part of this <br /> work beyond that perrjnitbed by U.S.copyright laws without the written permission of du Pont is <br /> unlawful and strictly forbidden. <br />