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MSDS 19-1 July 1,2002 TWA 0 None METHYL ISOBUTYL KETONE 1,2,4-TRIMETHYL BENZENE 108-10-1 15.0 A 75.0 ppm 95-63-6 7.0 @44.4°C A 25.0 ppm 15 min STEL 0 25.0 ppm A 50.0 ppm 0 100.0 ppm *A=ACGIH,O=OSHA,D=DuPont,S=Suppliers.Limits are 8 hour TWA unless OXO-OCTYL ACETATE otherwise specified. Vapor pressure @25*C unless otherwise noted. 108419- 2-5 0.7 @ 25.0°C S 50.0 ppm SECTION 3-Hazards Information Vapor S 10.0 mg/rr? Potential Health Effects: Aerosol Inhalation: A None May cause nose and throat irritation. May cause nervous system 0 None depression characterized by the following progressive steps: headache,dizziness,nausea,staggering gait,confusion, POLYESTER RESIN-A unconsciousness. Reports have associated repeated and prolonged Not Ava it None A None overexposure to solvents with permanent brain and nervous system 0 None damage. If this product contains or is mixed with an isocyanate activator/hardener,the following health effects may apply:Exposure POLYESTER RESIN-B to isocyanates may cause respiratory sensitization. This effect may 65086-7 -9 None A None be permanent. Symptoms include an asthma-like reaction with 0 None shortness of breath,wheezing,cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. PROPYLENE GLYCOL MONOMETHYL ETHEI 1,ACETATE Repeated overexposure to isocyanates may cause a decrease in lung 108-65 3.7 D 10.0 ppm function,which may be permanent. Individuals with lung or breathing 12 hr TWA problems or prior reactions to isocyanates must not be exposed to A None vapors or spray mist of this product. 0 None Ingestion: May result in gastrointestinal distress. SUBSTITUTED BENZOTRIAZOLE-B Sidn or eye contact: 127519-1;-9 9.0 @ 25.0°C A None May cause irritation or burning of the eyes. Repeated or prolonged 0 None liquid contact may cause skin irritation with discomfort and SYNTHETIC RESIN dermatitis. NotAvail None A None Other Potential Health Effects in addition to those listed above: 0 None ACETONE TOLUENE May cause irritation of the mucous membranes. The following 108-88-3 22.0 0 300.0 ppm medical conditions may be aggravated by exposure: CEIL respiratory system skin 0 200.0 ppm Repeated or prolonged liquid contact may cause skin irritation with D 50.0 ppm discomfort and dermatitis. Overexposure may cause damage to any 8&12 hour of the following organs/systems: blood eyes kidneys liver TWA respiratory system skin A 50.0 ppm Aspiration may occur during swallowing or vomiting,resulting in lung Skin damage. Material may be harmful or fatal if swallowed. 0 500.0 ppm Ingestion may cause headache,nausea,vomiting,dizziness,and 10 min TWA drowsiness. Maximum ALIPHATIC POLYISOCYANATE RESIN Overexposure may cause asthma-like reactions with shortness of XYLENE breath,wheezing,cough,which may be permanent;or permanent 1330-20- 9.0 @ 25.0°C A 150.0 ppm lung sensitization.This effect may be delayed for several hours after 15 min STEL exposure. The following medical conditions may be aggravated by D 150.0 ppm exposure:asthma lung disease bronchitis eczema skin disorders 15 min STEL May cause any of the following central nervous system effects: A 100.0 ppm breathing difficulties headache nausea vomiting 0 100.0 ppm Contact may cause skin irritation with discomfort or rash. D 100.0 ppm Repeated exposure may cause allergic skin rash,itching,swelling. 8&12 hour May cause eye irritation with discomfort,tearing,or blurred vision. TWA Can be absorbed through the skin in harmful amounts. Repeated overexposure to isocyanates may cause lung injury, 1,6 HEXAMETHYLENE DIISOCYANATE including a decrease in lung function,which may be permanent. 822-06-0 0.0 @ 25.0°C A 5.0 ppb Individuals with preexisting lung disease,asthma or breathing 2 MSDS 19-1 July 1,2002 p 2001-2002 E.I.du Pont de Nemours and Company.All rights reserved. Reproduction or translation of any part of this work beyond that per itted by U.S.copyright laws without the written permission of du Pont is unlawful and strictly forbidden.