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MSDS 19-1
<br /> July 1, 2002
<br /> disease of any of the following: central nervous system kidneys Full protective equipment,including self-contained breathing
<br /> liver respiratory system skin apparatus, is recommended.Water from fog nozzles may be used to
<br /> May cause eye irritation with discomfort,tearing,or blurred vision. prevent pressure build-up.
<br /> Can be absorbed through the kin in harmful amounts. Fire&explosion hazards:
<br /> Recurrent overexposure may result in liver and kidney injury. For flammable liquids,vapor/air will ignite when an ignition source
<br /> High airborne levels have produced irregular heartbeats in animals is present. In other cases,when heated above the flash point,emits
<br /> and occasional palpitations in humans. Rats exposed to very high flammable vapors which,when mixed with air,can bum or be
<br /> airborne levels have exhibited high frequency hearing deficits.The explosive.Fine mists or sprays may be flammable at temperatures
<br /> significance of this to man is unknown. Aspiration may occur during below the flash point.
<br /> swallowing or vomiting,resulti g in lung damage. Material may be
<br /> harmful or fatal if swallowed. SECTION 6-Accidental Release Measures
<br /> WARNING: This chemical is known to the State of California to cause
<br /> birth defects or other reproductive harm. Steps to be taken in case material is released or spilled:
<br /> Ventilate area. Remove sources of ignition.Prevent skin and eye
<br /> XYLENE contact and breathing of vapor. If the material contains,or is mixed
<br /> Increased susceptibility to the effects of this material may be with an isocyanate activator/hardener:Wear a positive-pressure,
<br /> observed in people with preexisting disease of any of the following: supplied-air respirator(NIOSH approved TC-19C),eye protection,
<br /> bone marrow cardiovascular stem central nervous system gloves and protective clothing. Pour liquid decontamination solution
<br /> kidneys liver lungs over the spill and allow to sit at least 10 minutes. Typical
<br /> Can be absorbed through the skin in harmful amounts. decontamination solutions for isocyanate containing materials are:
<br /> Can irritate or bum eyes. Recurrent overexposure may result in liver 20%Surfactant (Tergitol TMN 10)and 80%Water OR 0-10%
<br /> and kidney injury. High exposures may produce irregular heartbeats. Ammonia,2-5%Detergent and Water(balance) Pressure can be
<br /> Canada classifies Xylene as a developmental toxin as high exposures generated.Do not seal waste containers for 48 hours to allow CO2 to
<br /> to xylenes in some animal studies have been reported to cause health vent. After 48 hours,material may be sealed and disposed of
<br /> effects on the developing fetus/ mbryo.These effects were often at properly. If material does not contain or is not mixed with an
<br /> levels toxic to the adult animal. The significance of these effects isocyanate activator/hardener:Wear a properly fitted air-purifying
<br /> to humans is not known. Aspiration may occur during swallowing or respirator with organic vapor cartridges(NIOSH approved TC-23C),
<br /> vomiting,resulting in lung damz ge. Material may be harmful or fatal eye protection,gloves and protective clothing.Confine,remove with
<br /> if swallowed. Prolonged or rePE ated skin contact may cause drying, inertabsorbent,and dispose of properly.
<br /> cracking,or irritation.
<br /> 1,6 HEXAMETHYLENE DIISOCYANA E SECTION 7-Handling and Storage
<br /> Repeated overexposure may cal.se asthma-like reactions with Precautions to be taken in handling and storing:
<br /> shortness of breath,wheezing,cough or permanent lung sensitization. Observe label precautions.If combustible(flashpoint between 100-
<br /> The following medical conditions may be aggravated by exposure: 200°F),keep away from heat,sparks and flame.If flammable
<br /> Individuals with preexisting lung disease,asthma or breathing (flashpoint less than 1001F),also keep away from static
<br /> difficulties may have increased susceptibility to the toxicity of discharges and other sources of ignition.If material is extremely
<br /> excessive exposures. Repeated or prolonged skin contact may cause flammable(flashpoint less than 20°F)or flammable,VAPORS MAY
<br /> any of the following:severe imtition burns skin sensitization IGNITE EXPLOSIVELY OR CAUSE FLASH FIRE,respectively.Vapors
<br /> Eye contact may cause any of the following: burns may spread long distances.Prevent buildup of vapors.Close container
<br /> after each use.Ground containers when pouring.Wash thoroughly
<br /> SECTION 4-First d Measures after handling and before eating or smoking.Do not store above
<br /> 120°F. If product is waterbased,do not freeze.
<br /> First Aid Procedures: Other precautions:
<br /> Inhalation: If material is a coating:do not sand,flame cut,braze or weld dry
<br /> If affected by inhalation of vapo or spray mist,move to fresh air. coating without a NIOSH approved respirator or appropriate
<br /> If not breathing,give artificial respiration,preferably ventilation,and gloves.
<br /> mouth-to-mouth. If breathing di culty persists,or occurs later,
<br /> consult a physician. SECTION 8-Exposure Controls or Personal Protection
<br /> Ingestion:
<br /> In the unlikely event of ingestion DO NOT INDUCE VOMITING. Call Engineering controls and work practices:
<br /> a physician immediately and have names of ingredients available. Ventilation:
<br /> Skin or eye: Provide sufficient ventilation in volume and pattern to keep
<br /> In case of eye contact,immediat ly flush with plenty of water for at contaminants below applicable exposure limits.
<br /> least 15 minutes; call a physician In case of skin contact,wash Respiratory:
<br /> thoroughly with soap and water.If irritation occurs,contact a Do not breathe vapors or mists. If this product contains
<br /> physician. isocyanates or is used with an isocyanate activator/hardener,wear a
<br /> positive-pressure,supplied-air respirator(NIOSH approved TC-19C)
<br /> SECTION S-Firefighting Measures while mixing activator/hardener with paint,during application and
<br /> until all vapors and spray mist are exhausted. If product does not
<br /> Flash Point(Closed Cup) See Section)11 for exact values. contain or is not mixed with an isocyanate activator/hardener,a
<br /> Flammable limits LFL 0.9%UFL 13.1% properly fitted air-purifying respirator with organic vapor cartndges
<br /> Extinguishing media: (NIOSH TC-23C)and particulate filter(NIOSH TC-84A)may
<br /> Universal aqueous film-forming fc am,carbon dioxide,dry chemical. be used. Follow respirator manufacturers directions for respirator
<br /> Fire fighting procedures: use.Do not permit anyone without protection in the painting area.
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<br /> MSDS 19-1
<br /> July 1,2002
<br /> © 2001-2002 E.I. du Pont de Nemours and Company.All rights reserved. Reproduction or translation of any part of this
<br /> work beyond that permitted by U.S. copyright laws without the written permission of du Pont is
<br /> unlawful and strictly forbidden.
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