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Diamond Pet Food&AltaGas Ripon Energy January 31,2017 <br /> Combined Annual and Fourth-Quarter 2016 Groundwater-Monitoring Report Page I of 6 <br /> INTRODUCTION <br /> This report presents the combined annual summary report and the results of annual and fourth- <br /> quarter 2016 groundwater monitoring performed by Lawrence &Associates (L&A) on October <br /> 10 and October 11, 2016, for Diamond Pet Food Processors of Ripon California LLC (DP) and <br /> AltaGas Ripon Energy, Inc. (Ripon Energy), 942 South Stockton Avenue, Ripon, California <br /> (Figure 1). The work was performed in accordance with Waste Discharge Requirements <br /> (WDR) Order No. R5-2012-0105 for the DP/Ripon Energy site, adopted by the California <br /> Regional Water Quality Control Board, Central Valley Region(CVRWQCB) on October 4, <br /> 2012. <br /> Annual and fourth-quarter groundwater monitoring consisted of measuring the depth to <br /> groundwater in monitoring wells OB-1, OB-2, OB-4, OB-5, OB-7, OB-8, OB-11, OB-17, OB- <br /> 19, OB-21, OB-22, OB-24, OB-25, OB-26, and OB-28 (Figure 2) and collecting groundwater <br /> samples from the monitoring wells, as well as production wells PW-6, PW-7 and PW-8. <br /> Groundwater samples were field tested for temperature,pH, electrical conductivity(EC), and <br /> turbidity and laboratory tested for pH, EC, total dissolved solids (TDS; Figure 3), nitrate as <br /> nitrogen,boron, calcium, chloride, iron, magnesium, manganese, nitrogen, potassium, sodium, <br /> sulfate, total alkalinity(including alkalinity series), and hardness. <br /> Table 1 (following text)presents well descriptions including well names, casing diameter, <br /> reference point elevation, total depth, screened intervals, and aquifer unit(s). <br /> Table 2 (following text)presents annual and fourth-quarter groundwater field and laboratory <br /> data and Ripon Energy source water laboratory data. <br /> This report also includes (1) daily, weekly, monthly, and annual data collected by DP and Ripon <br /> Energy personnel, including wastewater and dilution water flow monitoring, influent <br /> monitoring, aeration stabilization basin(ASB) monitoring, effluent monitoring, and land <br /> application area(LAA) monitoring; (2) an evaluation of the performance of the waste water <br /> treatment facility(WWTF); (3) a description of progress in the implementation of the Salinity& <br /> Nutrient Evaluation Plan; (4) a statistical analyses of groundwater quality; and a description of <br /> the salinity sources control methods implemented in the calendar year. <br /> Data from offsite monitoring, domestic, and municipal wells is included herein. The offsite <br /> wells were sampled by Stantec for the City of Ripon or Environmental Cost Management <br /> (ECM) for Nestl6s. Field and laboratory results provided by Stantec and ECM were used in the <br /> preparation of this report and are presented in Attachment A. L&A, however, did not review <br /> the Stantec or ECM sampling methods or data for accuracy. <br /> COMPLIANCE RECORD <br /> During 2016, DP and Ripon Energy were in compliance with all report submittals and operation <br /> limitations set forth in WDR Order No. R5-2012-0105, with the following exceptions: <br /> 1. Treated DP and Ripon Energy effluent exceeded the upper concentration limit of 8.5 pH <br /> units for pH on January 13, March 9, April 6, June 8, July 6, August 12, September 14, <br /> November 6, and December 21, 2016 (Table 4). The annual average pH for effluent <br /> was 8.8 pH units. <br /> 2. An effluent water sample from ASB-2 was not collected for the month of October <br /> (Table 4). <br /> 010107.08 Task 4 Lawrence&Associates <br /> W ICLIENTSIDiamond Pet Foods1010107.01-Groundwater MonitoringlGroundwater Monitoring1201614QAnnua1201614TH QUARTER Annual 2016.do" <br />