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Diamond Pet Food&Ripon Cogeneration May 28,2014 <br /> Second-Quarter 2014 Groundwater Monitoring Report Page I of 5 <br /> INTRODUCTION <br /> This report presents the results of second-quarter 2014 groundwater monitoring performed by <br /> Lawrence &Associates (L&A) on April 7 and 8, 2014, at Diamond Pet Food Processors of <br /> Ripon California LLC (DP) and Ripon Cogeneration, LLC (Cogen), 942 South Stockton <br /> Avenue, Ripon, California(Figure 1). The work was performed in accordance with Waste <br /> Discharge Requirements (WDR) Order No. R5-2012-0105 for the DP/Cogen site, adopted by <br /> the California Regional Water Quality Control Board, Central Valley Region (CVRWQCB) on <br /> October 4, 2012. <br /> Second-quarter monitoring consisted of measuring the depth to groundwater in monitoring wells <br /> OB-1, OB-2, OB-4, OB-5, OB-7, OB-8, OB-11, OB-17, OB-19, OB-21, OB-22, OB-24, OB-25, <br /> OB-26, and OB-28, collecting groundwater samples from the wells and analyzing the samples <br /> for temperature,pH, electrical conductivity(EC), turbidity, total dissolved solids (TDS), and <br /> nitrate as nitrogen. <br /> Table 1 (following text)presents well descriptions including well names, casing diameter, <br /> reference point elevation, total depth, screened intervals, and aquifer unit(s). <br /> L&A sampled the wells located on the DP/Cogen site. All offsite monitoring, domestic, and <br /> municipal wells were sampled by Stantec for the City of Ripon or Environmental Cost <br /> Management(ECM) for Nestl6s. Field and laboratory results provided by Stantec and ECM <br /> were used in the preparation of this report and are presented in Attachment A. L&A, however, <br /> did not review the Stantec or ECM sampling methods or data for accuracy. <br /> SECOND-QUARTER 2014 GROUNDWATER MONITORING <br /> FINDINGS <br /> On April 7, 2014, a hydrologic divide was present in the west-central portion of the DP/Cogen <br /> site and in the vicinity of the City of Ripon's waste-water treatment facility(WWTF)ponds and <br /> fresh-water infiltration pond. The direction of the groundwater gradient north of the divide <br /> ranged between north-northeast (10°) and north-northwest (350°) at a magnitude of 0.00 13 ft/ft; <br /> the direction of the gradient south of the divide ranged between south-southeast(170°) and <br /> south-southwest (240°) at a magnitude ranging between 0.0018 and 0.00053 ft/ft. The direction <br /> of the gradient in the eastern portion of the DP/Cogen site was generally towards the northwest <br /> (2950) at a magnitude of 0.00085 ft/ft, however, adjacent to the Stanislaus River the gradient <br /> was towards the south-southwest(210°) at a magnitude of 0.0005 (Table 2; Figure 2). <br /> pH concentrations in all monitoring well samples were within the 6.5 to 8.5 standard pH units <br /> range for DP/Cogen effluent(Table 2). <br /> TDS concentrations in groundwater samples OB-4, OB-5, OB-24, OB-25, and OB-28 exceeded <br /> the 800 mg/L limitation for DP/Cogen effluent. The highest TDS concentration was measured <br /> in well OB-4 (1,900 mg/L) located in the eucalyptus grove in the northeast quadrant of the site <br /> (Figure 3). The lowest TDS concentration was measured in monitoring well OB-17 (130 <br /> mg/L), located in the southeastern corner of the site along the Stanislaus River. <br /> Nitrate as nitrogen concentrations in wells OB-5, OB-7, OB-8, OB-19, OB-21, OB-26, and OB- <br /> 28 exceeded the 10 mg/L limitation for DP/Cogen effluent. The highest nitrate concentrations <br /> were measured in wells OB-5 (17 mg/L) along the western site boundary and in wells OB-26 <br /> (23 mg/L) and OB-28 (35 mg/L; Table 2)just offsite of the northeastern quadrant of the site. <br /> 10107.06 Task 2 Lawrence&Associates <br /> W.-I CLIENTSIDiamond Pet Foods 1010107.01-Groundwater Monitoring)Groundwater Monitoring120M2Q20M2st quarter 2014 report.docx <br />