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Diamond Pet Food&Ripon Energy July 12,2016 <br /> Second-Quarter 2016 Groundwater-Monitoring Report Page I of 5 <br /> INTRODUCTION <br /> This report presents the results of second-quarter 2016 groundwater monitoring performed by <br /> Lawrence &Associates (L&A) on April 4 and 5, 2016, at Diamond Pet Food Processors of <br /> Ripon California, LLC (DP) and AltaGas Ripon Energy, Inc. (Ripon Energy), 942 and 944 <br /> South Stockton Avenue, Ripon, California(Figure 1). The work was performed in accordance <br /> with Waste Discharge Requirements (WDR) Order No. R5-2012-0105 for the DP/Ripon Energy <br /> site, adopted by the California Regional Water Quality Control Board, Central Valley Region <br /> (CVRWQCB) on October 4, 2012. <br /> Second-quarter monitoring consisted of measuring the depth to groundwater in monitoring wells <br /> OB-1, OB-2, OB-4, OB-5, OB-7, OB-8, OB-11, OB-17, OB-19, OB-21, OB-22, OB-24, OB-25, <br /> OB-26, and OB-28, collecting groundwater samples from the wells and analyzing the samples <br /> for temperature,pH, electrical conductivity(EC), turbidity, total dissolved solids (TDS), and <br /> nitrate as nitrogen. <br /> Table 1 (following text)presents well descriptions including well names, casing diameter, <br /> reference point elevation, total depth, screened intervals, and aquifer unit(s). <br /> L&A sampled the wells located on the DP/Ripon Energy site. All offsite monitoring, domestic, <br /> and municipal wells were sampled by Stantec for the City of Ripon or ECM Consultants for <br /> Nestl6s. Field and laboratory results provided by Stantec and ECM Consultants were used in <br /> the preparation of this report and are presented in Attachment A. L&A, however, did not <br /> review the Stantec or ECM Consultants sampling methods or data for accuracy. <br /> SECOND-QUARTER 2016 GROUNDWATER MONITORING <br /> FINDINGS <br /> On April 4, 2016, the direction of the groundwater across the DP/Ripon Energy site was <br /> generally towards the northwest (204°to 3070) at a magnitude ranging between 0.002 and <br /> 0.0007 ft/ft. West of the site, a mound was present in the uppermost groundwater unit in the <br /> vicinity of the City of Ripon's waste-water treatment facility(WWTF)ponds and fresh-water <br /> infiltration pond. The mound extended eastward onto the western portion of DP/Ripon Energy <br /> site (Table 2; Figure 2). <br /> The pH concentrations in all monitoring wells were within the 6.5 to 8.5 standard pH units <br /> range for DP/Ripon Energy effluent (Table 2). <br /> TDS concentrations in groundwater samples OB-4, OB-5, OB-24, OB-25, and OB-28 exceeded <br /> the 800 mg/L limitation for DP/Ripon Energy effluent. The highest TDS concentration was <br /> measured in well OB-4 (1,300 mg/L) located in the eucalyptus grove in the northeast quadrant <br /> of the site (Figure 3). The lowest TDS concentration was measured in monitoring well OB-17 <br /> (80 mg/L), located in the southeastern corner of the site along the Stanislaus River. <br /> Nitrate as nitrogen concentrations in wells OB-1, OB-5, OB-26, and OB-28 met or exceeded the <br /> 10 mg/L limitation for DP/Ripon Energy effluent. The highest nitrate concentration was <br /> measured in well OB-28 (75 mg/L; Table 2)just offsite of the northeastern quadrant of the site. <br /> 10107.08 Task I Lawrence&Associates <br /> W.-I CLIENTSIDiamond Pet Foods 1010107.01-Groundwater Monitoring)Groundwater Monitoring1201612QM M2Q quarter 2016 report.docx <br />