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Diamond Pet Food&Ripon Energy July 23,2018 <br /> Second-Quarter 2018 Groundwater-Monitoring Report Page I of S <br /> INTRODUCTION <br /> This report presents the results of second-quarter 2018 groundwater monitoring performed by <br /> Lawrence &Associates (L&A) on April 2 and 3, 2018, at Diamond Pet Food Processors of <br /> Ripon California, LLC (DP) and A1taGas Ripon Energy, Inc. (Ripon Energy), 942 and 944 <br /> South Stockton Avenue, Ripon, California (Figure 1). The work was performed in accordance <br /> with Waste Discharge Requirements (WDR) Order No. R5-2012-0105 for the DP/Ripon Energy <br /> site, adopted by the California Regional Water Quality Control Board, Central Valley Region <br /> (CVRWQCB) on October 4, 2012. <br /> Second-quarter monitoring consisted of measuring the depth to groundwater in monitoring wells <br /> OB-1, OB-2, OB-4, OB-5, OB-7, OB-8, OB-11, OB-17, OB-19, OB-21, OB-22, OB-24, OB-25, <br /> OB-26, and OB-28, collecting groundwater samples from the wells and analyzing the samples <br /> for temperature, pH, electrical conductivity(EC), turbidity, total dissolved solids (TDS), and <br /> nitrate as nitrogen. <br /> Table 1 (following text)presents well descriptions including well names, casing diameter, <br /> reference point elevation, total depth, screened intervals, and aquifer unit(s). <br /> L&A sampled the wells located on the DP/Ripon Energy site. All offsite monitoring, domestic, <br /> and municipal wells were sampled by Stantec for the City of Ripon or ECM Consultants for <br /> Nestles. Field and laboratory results provided by Stantec and ECM Consultants were used in <br /> the preparation of this report and are presented in Attachment A. L&A, however, did not <br /> review the Stantec or ECM Consultants sampling methods or data for accuracy. <br /> SECOND-QUARTER 2018 GROUNDWATER MONITORING <br /> FINDINGS <br /> On April 2, 2018, the direction of the groundwater gradient across most of the DP/Ripon Energy <br /> site was northwest and ranged between 263°to 291° at a magnitudes between 0.00028 and <br /> 0.00054 ft/ft. In the southwestern quadrant of the site the direction of the gradient was 221° <br /> southwest at a magnitude of 0.00063 ft/ft. (Table 2; Figure 2). <br /> The pH concentrations in all monitoring wells were within the 6.5 to 8.5 standard pH units <br /> range for DP/Ripon Energy effluent(Table 2). <br /> TDS concentrations in groundwater samples OB-1, OB-4, OB-11, OB-24, OB-25, and OB-28 <br /> exceeded the 800 mg/L limitation for DP/Ripon Energy effluent. The highest TDS <br /> concentrations were measured in wells OB-4 and OB-25 (1,500 mg/L, respectively) located in <br /> the eucalyptus grove in the northeast quadrant of the site and in the southwestern quarter of the <br /> site (Figure 3). The lowest TDS concentration was measured in monitoring well OB-22 (100 <br /> mg/L), located in the south central portion of the site between ASB-2 and the Stanislaus River. <br /> Nitrate as nitrogen concentrations in wells OB-1, OB-26, and OB-28 exceeded the 10 mg/L <br /> limitation for DP/Ripon Energy effluent. The highest nitrate concentration was measured in <br /> well OB-28 (56 mg/L; Table 2)just offsite of the northeastern quadrant of the site. <br /> CONCLUSIONS <br /> The past disposal of plant process water by the former paper-making facility was responsible for <br /> some of the elevated TDS levels measured in the semiperched aquifer over most of the site. <br /> Since the facility's conversion to a pet food manufacturing facility, however,plant effluent has <br /> 10107.10 Task 2 Lawrence&Associates <br /> W.•ICLIENTYDiamond Pet Foods 1010107.01-Groundwater Monitoring)Groundwater MonitoringQ01812Q2018QQ quarter 2018 report.docx <br />