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APP_X ErJVJROTECH, IlVC. <br /> STANDARD OPERATING PROCEDURES <br /> Quarterly Monitoring Reports <br /> sop - A When practical,the groundwater sample should be collected <br /> SAMPLE IDENTIFICATION AN13 CHAIN- when the water level In the well recovers to at least 80 percent <br /> OF-CUSTODY PROCEDURES of its static level <br /> Sample identification and chain-of-custody procedures ensure The sampling equipment consists of either a Teflon"bailer, <br /> y sample integrity as well as document sample possession from PVC bailer,or stainless steel bladder pump with a"Teflon" <br /> the time of collection to ultimate disposal Each sample bladder If the sampling system is dedicated to the we1i,then <br /> the ti mer submstt collection <br /> far analysis is labeled to Identify the job the bailer is usually"Teflon,' but the bladder pump is PVC with <br /> a polypropylene bladder In general and depending on the <br /> number,date,time of sample collection,a sample number intended laboratory analysis,40-mtllrUter glass,volatile organic <br /> unique to the sample,any in-field measurements made, analysis(VOA)vials,with"Teflon"septa,are used as sample <br /> sampling methodology,name(s)of on-site personnel,and any containers <br /> other pertinent field observations also recorded on the field <br /> excavation or boring log SOP - 10 <br /> MEASURING LiQUID LEVELS USING <br /> Chain-af-custody forms are used to record possession of the WATER LEVEL. METER OR INTERFACE <br /> sample from time of collection to arrival at the laboratory PROSE <br /> During shipment,the person with custody of the samples will <br /> relinquish them to the next person by signing the chain-of- field equipment used for liquid-level gauging typically includes <br /> custody rorm(s)and noting the date and time The sample- the measuring instrument(water-levet meter or interface probe) <br /> control officer at the laboratory unit verify sample Integrity, and product bailer(s) The field krt also includes cleaning <br /> correct preservation,confirm collection in the proper supplies(buckets,solution,spray bottles,and deion¢ed water) <br /> container(s),and ensure adequate volume for analysis to be used in cleaning the equipment between wells <br /> If these conditions are met,the samples will be assigned Prior to measurement,the instrument tip is lowered into the well <br /> unique laboratory log numbers for identification throughout until it touches bottom Using the previously established top-of- <br /> analysis and reporting The log numbers will be recorded on casing or top-of-box(i e,wellhead vault)point,the probe cord <br /> the chain-of-custody forms and in the legally-required log book (or halyard)is marked and a measuring tape(graduated in <br /> maintained in the laboratory The sample description,date hundredths of a foot)is used to determine the distance <br /> received,client s name,and any other relevant information wit between the probe end and the marking on the cord This <br /> also be recorded measurement is then recorded on the liquid-level data sheet as <br /> the"Measured Total Depth of the well <br /> SOP " is When necessary in using the interface probe to measure liquid <br /> LA130RATO RY ANALYTICAL gUALl7Y levels,the probe is first electrically grounded to either the metal <br /> ASSURANCE AND CONTROL stovepipe or another metal object nearby When no ground is <br /> available,reproducible measurements can be obtained by <br /> In addition to routine instrument calibration,replicates,spikes, clipping the ground lead to the handle of the interface probe <br /> blanks,spiked blanks,and certified reference materials are case <br /> routinely analyzed at method-specific frequencies to monitor <br /> The probe <br /> precision and bias Additional components of the laboratory hp is then lowered into the well and submerged in <br /> Quality Assurance/Qualety Control program include the groundwater An oscillating(beeping)tone indicates the <br /> probe is in water The probe Is slowly raised until either the <br /> I Participation in state and federal laboratory oscillating tone ceases or becomes a steady tone In either <br /> accreditation/certirication programs, case,this is the depth-to-water(DTW)Indication and the DTW <br /> measurement is made accordingly The steady tone Indrcates <br /> 2 Participation in both U S EPA Performance floating liquid hydrocarbons(FLH) in this case,the probe Is <br /> Evaivation studies(WS and WP studies)and Inter- slowly raised until the steady tone ceases This is the depth-to- <br /> laboratory performance evaluation programs, product(DTP)indication and the DTP measurement is made <br /> accordingly <br /> 3 Standard operating procedures describing routine <br /> and periodic Instrument maintenance, The process of lowering and raising the probe must be <br /> repeated several times to ensure accurate measurements The <br /> 4 "Out-of-Control"/Corrective Action documentation DTW and DTP measurements are recorded on the liquid-level <br /> procedures,and, data sheet When FLH are Indicated by the probe's response, <br /> a product bailer is lowered partially through the FLH-water <br /> 5 Mutts-level review of raw data and client reports Interface to confirm the FLH on the water surface and as <br /> further indication of the FLH thickness,particularly in cases <br /> SOP - 7 where the FLH layer is quite thin This measurement is <br /> GROUNDWATER PURGING AND recorded on the data sheet as`FLH thickness" <br /> SAMPLING <br /> In order to avoid cross-contamination of wells during the liquid- <br /> Prior to water sampling,each well is purged by evacuating a level measurement process,wells are measured in the order of <br /> minimum of three wetted well-casing volumes or groundwater "clean"to"dirty"(where such information is available) In <br /> When required,purging will continue until either the discharge addition,all measurement equipment Is cleaned with solution <br /> water temperature,conductivity,or pH stabilize,a maidmurn of and thoroughly rinsed with deionized water before use,between <br /> ten wetted-casing volumes of groundwater have been measurements in respective wells,and at the completion of the <br /> recovered,or the well is bailed dry days use <br />