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d <br /> i <br /> analysis of TPHg and BTEX by EPA Methods 8015m and 8020. All laboratory analyses <br /> shall be performed by a State='certified laboratory. Parameters to be monitored and <br /> adjusted in the field shall include vapor extraction flow rates, air injection flowrates, <br /> induced vacuum responses at on-site wells if applicable, and hydrocarbon vapor <br /> concentrations with an organic vapor monitor approved by the SJVUAPCD. <br /> Monitoring and sampling of five existing groundwater wells and two selected vapor <br /> extraction wells shall continue on a quarterly basis. Sampling consists of collecting <br /> groundwater samples for analysis of TPHg and TPHd by EPA method 8015m, BTEX by <br /> EPA method 8020, and for fuel oxygenates by EPA method 8260. <br /> Section 10.8 Vapor Extraction and Air Sparge Systems Sampling <br /> Typical SJVUAPCD guidelines :;require that during the startup phase of the off-gas <br /> abatement unit, influent and effluent air samples to the VES be collected to evaluate <br /> destruction efficiency of the unit. Sampling consists of collecting air samples for submittal <br /> to a State-certified laboratory for analysis of TPHg and BTEX by EPA methods 8015m and <br /> 8020. <br /> To demonstrate compliance with SJVUAPCD regulations, the VES shall be sampled at <br /> least once during the first week of operation, and once per month for the life of the <br /> remediation system. With the exception of influent and effluent air samples collected and <br /> analyzed as detailed above, during the first 2 days of operation and later on a biweekly <br /> and monthly t basis all other sampling of the VES shall <br /> Y � be conducted usingafield organic <br /> P 9 <br /> g <br /> vapor monitoring instrument approved by the SJVUAPCD. <br /> If at any time the results of laboratory analyses or field monitoring readings show emission <br /> limits to be exceeded, a confirmation air sample shall be taken immediately and analyzed <br /> on a 24-hour turnaround basis by a State-certified laboratory for TPHg and BTEX by EPA <br /> methods 8015m and 8020. If emission limits are shown to be exceeded, the system shall <br /> be shut down and any necessary'-corrective action shall be performed before repeating the <br /> startup sequence. SJVUAPCD shall be notified that emission limits were exceeded within <br /> 24 hours of such indication. <br /> Vapor phase granulated activated carbon is a proven technology and destruction <br /> efficiency is not anticipated to be a concern. Having two canisters in series shall provide a <br /> safeguard against exceeding emission limits. Monitoring vapors from the sampling port in <br /> between the two canisters should provide an indication when breakthrough has occurred. <br /> This shall allow sufficient time to`'change out the carbon if necessary prior to emission to <br /> the atmosphere. Typical SJVUAPCD guidelines require that extracted vapor influent to <br /> and effluent from the carbon system shall be monitored with a field instrument approved <br /> by the SJVUAPCD on a daily basis until the frequency of carbon changeout .can be � <br /> evaluated. System monitoring frequency, if applicable, shall be changed to once every 2 <br /> weeks or monthly, with a field instrument and monthly verification by analytical laboratory <br /> testing upon receiving SJVUAPCD approval.. <br /> Section 10.9 Vapor Extraction System and Air Sparge System Performance <br /> Evaluation <br /> Following continued operation of the VES and air sparge system, a systems performance <br /> evaluation shall be conducted to monitor the effectiveness of the remediation systems, <br /> and a report shall be issued on a quarterly basis. This report shall, at a minimum, include <br /> the following: hours of operation,; system influent and effluent field monitoring readings; <br /> laboratory results of influent and effluent air samples; total and individual vapor extraction <br /> SP10 <br />