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Ben Hall -2- 5 November 2007 <br /> Musco Family Olive Company <br /> wastewater and runoff information is routinely collected at the site, but Kennedy Jenks needs <br /> to ensure that sufficient data is collected to meet the data quality objectives for this study. <br /> Under the first bullet item of Section 3.1 of the Work Plan, ash content is noted as a surrogate <br /> for fixed dissolved solids. This item also states that general minerals will be analyzed for one <br /> harvest per test plot per year. Kennedy Jenks needs to establish the nature of the correlation <br /> between ash content and specific cations and anions at the beginning of the study to ensure <br /> useful and understandable results. <br /> Under the second bullet item of Section 3.1, the analyte list for root zone soil sampling needs <br /> to include, at a minimum, those constituents listed in Item 12 on page 18 of the Cease and <br /> Desist Order. For example, bicarbonate is a key constituent of Musco's wastewater, but it is <br /> not discussed in the Work Plan. Its fate in the environment may differ from the other salts and <br /> needs to be addressed. The appropriate constituents need to be added to the analyte lists and <br /> included in the data evaluation <br /> Under Section 3.2 Study Locations, Kennedy Jenks describes three locations for the test plots <br /> and an unspecified number of additional monitoring locations for soil water monitoring and flux <br /> analyses. At least one test plot should be added in an area where tailwater and stormwater <br /> pond in the vicinity of the sumps or mud boxes (e.g., at the toe of Field 95-20). While these <br /> areas are small and do not represent the land application area as a whole, we believe they do <br /> represent the areas of highest flux due to saturated soil conditions. <br /> The activities proposed in the Work Plan may proceed provided Musco and Kennedy Jenks <br /> address the above factors as the work begins. <br /> Additional Concerns <br /> We identified the following concerns in our review of the Work Plan and believe they need <br /> additional consideration by Kennedy Jenks. While the Work Plan proposes methods to assess <br /> moisture and waste constituent distribution in the soil column, it does not propose to assess <br /> the actual total and remaining assimilative capacity of the soil. The Work Plan must propose <br /> work necessary to comply with Task 12 of CDO No. R5-2007-0139, including preparation of a <br /> salt balance. In addition, it needs to discuss how the chemical and physical characteristics of <br /> the soil affect the fate and transport of the constituents of concern (i.e., nitrogen compounds, <br /> bicarbonate, sulfate, iron, sodium, chloride, volatile/organic dissolved solids, etc.). For <br /> example, the annual soil monitoring results submitted to our office show that sodium is <br /> accumulating in at least the upper six inches of soil. Chloride, however, despite the discharge <br /> to,land of approximately 260 tons in 2005 and approximately 400 tons in 2006, does not <br /> appear to be accumulating at any of the three soil depths currently monitored. As chlorideis <br /> neither degraded nor transformed in the soil column, the Work Plan must be revised to explain <br /> how you intend to evaluate the fate of chloride at the site. This is critical in light of the Soil <br /> Profile and Agronomic Report for 2006, dated 31 January 2007, which stated that "[b]ased on <br /> sodium and chloride in NyPa forage samples, removal of more salt than applied is not <br /> projected." The Work Plan needs to be revised to include a salt balance, an assessment of <br /> the assimilative capacity of the soil for specific waste constituents, and a discussion of how <br /> chemical and physical characteristics affect constituent fate and transport. <br />