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• Water, Contaminant Removed <br /> C = 12,200 gal x 0 000042 ppm = 0 51 gal TPHG <br /> C = 12,200 gal x 0 000003600 ppb = 0 043 gal Benzene <br /> C = 12,200 gal x 0 000000058 ppb = 0 0007 gal MTBE <br /> Discussion- Excavated and Residual Contaminant Mass <br /> The calculated estimates indicate that very low quantities of residual contaminants are present <br /> both in the capillary fringe and in area of former tank pit/well MW-1 The range of <br /> concentrations suggests that these residuals, as well as those in excavated soil, were absorbed <br /> onto the soil Column experiments have demonstrated that soil absorption may hold from about <br /> 9% to 25% of the total spill hydrocarbon mass (Wilson and other, 1988) The lack of <br /> hydrocarbons at well MW-4 supports this assumption Current working models of MTBE suggest <br /> more rapid solubility and movement than BTEX fuel components However, only one occurrence <br /> of MTBE was observed in well MW-2, hence MTBE presence and movement is interpreted as <br /> negligible <br /> The observed soil sample and monitoring data above show that BTEX contaminants (the most <br /> prevalent on-site) are effectively immobile Well MW-4, located on the most conservative <br /> . flowline (and historically most consistent flow trend) has shown only three separated occurrences <br /> of low concentrations of TPHG In our opinion, this further substantiates the conclusion of <br /> absorbed and immobile contaminants are minimal <br /> Rationale for Residual Remaining Contaminants Fate <br /> The site assessment showed that a small dissolved plume of TPHG and BTEX arose from the <br /> former tanks and pit The underground storage tanks were removed in 1991 Contaminants <br /> absorbed in the soil posed a residual contaminant source, which was removed in 1999 A deep <br /> boring (B-14) sampled soil and groundwater at depth intervals below the former tank pit These <br /> soil samples showed that contaminants were not observed in soil samples B-14 groundwater <br /> samples collected at the 16 to 20-foot depth interval and 28 to 32-foot depth interval showed that <br /> both TPHG and Benzene substantially declined, and MTBE was not observed in either water <br /> sample <br /> The 1999 soil excavation removed additional contaminated soil and groundwater Perimeter soil <br /> samples revealed residual contaminants at the capillary fringe and base of excavation (see Figure <br /> 4) MTBE was observed in the base of excavation samples, however it was not present in the <br /> adjacent deeper samples of B-14 This contaminant distribution indicates these contaminants are <br /> residual absorbed onto soil Minor residual contaminants may remain just under East 1 pth <br /> Street, however, the excavation could not enter the street A calculated estimate of TPHG and <br /> Benzene show that very low quantities of both contaminants remain in soil and capillary water <br /> It is anticipated that these residual soil and water contaminants will degrade with time through in- <br /> Page 7 <br />