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<br /> 317 Tolu,nC
<br /> 9l92 } et Or ons: CNS,lives,
<br /> .:,
<br /> ction 6- Health Ha7.ard Data osure:Alcoholism and CNS.lidncy,skin or lieu disease•Target €
<br /> tion.Acute Effects:Vapor inhalation causes respiratory tract irritation.fatigue,
<br /> cdical Conditioac Aggravated b} Long Term Exp
<br /> itsc}',skin.Primary -ntry Routes:Inhalation,skinil n watering eves,nervousness,insomnia.para
<br /> sthesis,and vertigo progressing to narcotic coma.
<br /> e cau
<br /> _al mess,confusi°n,dizziness,"headache,dilated pup and fissured dermatitis•Ingestion causes GI tract irritation and -
<br /> ses conjunctival
<br /> ines
<br /> =ath ma
<br /> v result from cardiac arrest due to ventricular fibrillatintact].ads to drying an loss:Liquid splashed to the vyerli o nausea, loss and•
<br /> toms include mucous membrane irritation,headache,d g ement and
<br /> :nsient corneal damage and possible diems,Prolonged skin co
<br /> mptoms associated with inhalation.Chronic Effects:Symp worsen at weeks end and decrease or disappear aver the weekend.
<br /> v exposure may result in encephalopathies(cerebellar ataxia and cognitive dysfunction),liver en arg
<br /> _ohol intolerance.Repeated heavy pa at workdays end•
<br /> An dystrophy(wasting away):Symptoms usually appear es tightly shut Gently lift eyelids and flush immediately and continuously with flooding
<br /> 1 RST AID Eyes:Do mar allow victim tom en r keep
<br /> ya]facility.Consult an ophthalmologist immediately Skin:Quickly remove contaminated t
<br /> Haunts of water until transported to an em g y Wash exposed area with soap and water.Inhalation:Remove exposed person to
<br /> thin b mouth to an unconscious or convulsing Person.Contact a poison control
<br /> lathing.Rinse with flooding amounts Of 1ater estiont Naesver give any g Yo
<br /> resh air and support breathing as need g against.
<br /> ,e ter and unless otherwise advised,have that conscious and alert person drink amounts are swallowed potentialttoxic Do ty needs t.i e weighed al induce vomiting g se o
<br /> n
<br /> ',anger of aspiration into the.lungs.Gasephrine and other
<br /> tric lavage may be in
<br /> if large emir effects of such substances.Obtain CBC•
<br /> ation risk when deciding for or against gastric lavage.we t�tmP >a al t�hold the tarrhythmog Iflost potential
<br /> benzene toxicity.BEI:
<br /> 3spu 00 m)benzene,evaluatep
<br /> -3Lecholamines carefully,because of the possibility s If toluene has>0.02%(2 le at shift end(1.0 mglL).:
<br /> electrolytes,and urinalysis.Monitor arteria]blood c cotinine);Toluene in venous blood,same
<br /> hippuric acid in urine.sample at shift end(2 5 glg -
<br /> and sta u wmd.Cleanup personnel protect against inhalation and skwcye
<br /> Section 7, Spill,:Leak,and Disposal Procedures aces Celsosnel protect
<br /> hycar absorbent materials,and .
<br /> Spill!Leak.Notify safen,personnel.'icolatc and ventilate area eny not revent igniti n in closed sp vermiculite,or other absorbent, .. i
<br /> contact.Use water spray to cool and disperse vapo S but it may
<br /> yt not rat Take up small spill with earth'sand,ppm ar eater)apply activated carbon at
<br /> fluorocarbon water can also be used for vapor supe to remove immobilized masses of pollutants
<br /> nonco
<br /> fluorocarbon
<br /> material.Dike far ahead of large spills for later reclamation or disposal.For water spills.(1
<br /> material with suction hoses or use mechanical dqo C)lhot kiln incineration at 1508 to 2912•F(820 to
<br /> 1 OX the spilied amount and remove trapped 36,2
<br /> at bed incinerationFollow applicable OSHA regulations(29 CFR 19;�le�)): taoxicity k +
<br /> and precipitates. Toluene injectionan unnerati n atdergo d1202 to 2912-F(650 to 84600 C)95,4 3(450 to
<br /> fatheadd mmnavr(pi�phal's p
<br /> 1600•C),or 1 q4 hr,shrimp(Cran10 land.is comm),L Cso— pP
<br /> toluene volatilizes
<br /> alias:Blue gill,LCA_"17 mglLfL produced hydroxyl radicals•
<br /> air,toluene degrades by reaction with photochenucslly pr t
<br /> mglLl9
<br /> 6 hr.Environmental Degradation:If released t°land,toluene evaporates and undergoes microbial degradation.3 mediaIn
<br /> �luatian and carbon
<br /> and biodegrades with a half-life of days to several weeks.I vi separator.Contact your supplier ora y
<br /> Disposal:Treat contaminated water by gravity separation of solids,followed by slamming of surface.Pass g
<br /> absorption units(carbonra io I keturn waste water from b3
<br /> &mlmendationsj Fo1lo�alpplliicab a Federal,state,and opal egu ations•ry
<br /> licensed contractor forY OSHA Designations ,
<br /> EPA Designations Listr_d as an Air Cntaminant(29 ClR 1910.1000,Table Z 1-A) f
<br /> Listed as a RCRA Hazardous Waste(40 CFR 261.33):No.UNot7isted "`� 1DDO lb(454 kg)
<br /> SARA Extremely Hazardous Substance ce CFR 0CFR 02Q):Final Reportable Quaritity(RQ), a
<br /> Listed as a CERCLA Hazardous Substance ( CWA,Sec.307(a)] ~ '
<br /> (-per RCRA,Sec.3001;CWA.Sec.311 (b)(4);
<br /> Listed as a SARA Toxic Chemical(40 CFR 372.65):Not listed and face•protection
<br /> y"goggles.per OSHA ey
<br /> Section"$: Special Protection Data 11e Resplrator•Seek professional
<br /> Goggles:Wear protective eyeglasses with shatter-resistant glass and ss controversial,
<br /> si chemical safer 8 gg p wear a MSHA/N105H-
<br /> ',rotor re mations(29 CFR 1910.134)and,if nessar�artny supplied-air respirator
<br /> regulations(29 CFR 1910.133)..Becauseeontact lens use in industry is cantroversral,establish your own P°
<br /> e re instar with appropriate
<br /> r SCBA with ulgl faceprece,or any air-ptuifYin$
<br /> advice prior to respirator selection and use.Follow OSHA resp g pporganic vapor
<br /> approved respirator.For<100 ppm,use any chervil iatcontinuous-flow mode.any envy or nonroutine aperatioru(cleaning
<br /> (5AR),or S. For<200 ppm ,use any SAR op en-def cient amospheres_
<br /> with a full facepiece having a chin-style,front or back mounted organic vapor canister.For g
<br /> rrsPrrat°r weal an SCBA.Warning!Air-purr in res ',rotors da no!procto al ceriS in oxygen-d.
<br /> spills,reactor vessels,or storage tanks), protection program that includes at least medical eerttficatioe training,fit-uroizz
<br /> If respirators are used,OSHA requires a written respiratory pr and convenient,sanitary storage areas.Other:Wear chemically protective
<br /> g tenance,inspection:cleaning, a of>8 hr.Teflon and Viton are recom {
<br /> periodic environmental monitoring.main
<br /> gloves,boot,aprons.and gaubee
<br /> ntlets to prevent skin contact Polyvinyl alcohol with a breakthrough rite systems t Into the work area by econcentrations
<br /> entration a at its
<br /> as suitable materials for,PPF.•Ventilation.Provide genebecause i prevenntnd local s conetaminanttdupers to maintain w hing f cilities. ow
<br /> mended exhaust ventilation is preferred uick-dsench showers,
<br /> the OSHA FELs(Sec.2).Local eyewash stations.saferyiqour shoes and
<br /> source 003)S2fCty Stations:Make available in the work area emerge ey especially
<br /> before eating;
<br /> good personal hygiene after using this rrralersal,espec y
<br /> Contaminated Equipment:Separate costars aced work work arras.Practice et clothes and launder before reuse,Remove toluene m y
<br /> clean PPE.Comments:Never eat.drink»OT
<br /> cosmetics.
<br /> drinking„smoking,.using the toilet,os applying ."
<br /> _ we
<br /> area away from ignition sources andent static
<br /> Section 9. incorn-
<br /> $peci:�i Precautions and Comments
<br /> Strne in a cool.dry.
<br /> Storage Requirements:prcveritphsre�e If stared inside~use a standard flamrnzblc liquids warehouse:room,-or cabinet Top
<br /> patibles.Outside or detached storagepreferred.
<br /> used with toluene.Do not use open lights in toluene areas-Installclass I.� �electrical
<br /> spoils.elec:ricall} ground and bond all equip
<br /> eouipment.Check that toluene is free of or contains<I'o
<br /> benzine c before use.Engineering Controls: reduce potential
<br /> wells.storage tanks).
<br /> r 1910.[46)if entering areas of unknown toluene anti skin.include hemocytometnc
<br /> rcpt dilution or local exhaust ventilation to control airy a contaminant and m maintain concentrations at the Iowa[practical level:Adminis
<br /> su,fic aces 29 C
<br /> erative Controls:Adopt controls los confined spaces( workus that emphasize the CNS,liver.kids y.
<br /> Consider prcplaccmcm and periodic medical exams of exposed
<br /> tc count in cases where benzene is a contaminant of toluene.Monitor air at regular intervals to ensure effective ventilation.
<br /> and thramhocy Transportatlon Data(49 CFR 172.101) Vessel Stowage Requirements
<br /> ` uanilty Limitations Vessel Stowage:B
<br /> a}Exceptions:]50 a)Passenger Aircraft or Railcar:SL Other:—
<br /> DOT Shipping Name:Toluene a)Exc pti Authorizations ' Q)Car o Aircraft Only:60L
<br /> DOT Hazard Class:3 b)Non-bulk Packagln;:20_ €
<br /> ID NO.:UN1294 r
<br /> )Bulk!ackaging:24.
<br /> DOT I'ackin Group:II .: . - .,. :, • ,. F�'
<br /> DOT Label.Flt
<br /> ammabic Liquid
<br /> Special Provisions (172.10):T1
<br /> 167,169,171,"174,175,176,180.
<br /> hfSDS Collection Referentes:26,'73.100,101,l03,124.126,127-132,140.146,153,159.163,164, Y
<br /> iene Review•:f A Ra}'.CiH,MPH:Medicos Review:AC Darlrnluion�Dui p1�����rz�tM����,ryp�.
<br /> red bv;M Ganriat.RA:lndusirial HyF �- Y, �:.ve.rud —
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