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f , <br /> i <br /> Petroleum fuel consists of hundreds of chemical compounds. There are certain <br /> compounds such as benzene that present significant hazards and must be properly <br /> J. <br /> controlled. To do so, a working limit of 100 ppm total hydrocarbon is proposed as the <br /> maximum acceptable level of exposure without respiratory protection. In a typical <br />{ situation with 1% of the hydrocarbon vapors being benzene; a 100 ppmv concentration <br /> I of total hydrocarbon will result in a breathing zone of less than 1 ppmv benzene. This <br /> level is one tenth of the current occupational Permissible;Exposure Limit (PEL) <br /> Action Levels of Hydrocarbon Comvonents in Petroleums Fuel <br /> ' Gasoline >300ppm PEL LEL >10% <br /> P <br /> Benzene >lppm PEL Oxygen <19.5% <br /> Toluene >I 00ppm PEL <br /> Xylene >100ppm PEL <br /> Ethyl Benzene >I 00ppm PEL <br /> A hydrocarbon vapor analyzer will be used to measure real time breathing zone <br /> concentration for comparison with the 100 ppmv working[limito When a persistent level of <br /> J 100 ppmv is observed, appropriate respirators will be donned and other vapor measurements <br /> will be made. If hydrocarbon vapors exceed 1000 ppmv or 10 ppm benzene, work will be <br /> stopped. The field crew will be instructed to stay up wind and methods will be applied to <br /> subdue fugitive vapor emissions such as sprinkling soil with water, or. the use of a copus <br /> blower. <br /> The site Safety Officer will make such determinations. - <br /> If LEL is >10% in or around the tank, work must stop ana not commence until determined <br /> t t safe and/or LEL <10%. <br /> r If oxygen levels in the immediate work area are <19.5% ,11work-must stop until determined <br /> safe and/or LEL >19.5%. <br /> SSrnytorns of Acute Overexposure <br /> Gasoline and gasoline;vapors maybe irritating to the skin, eyes and respiratory tract. <br /> Gasoline vapors may effect the central nervous system and may cause headaches and �r. . <br /> dizziness. E <br /> ? A:\HEAL&SAF\TANK.001 29 January 1993 <br /> 5 Y <br /> I <br />