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Ms. Kathleen Minahan - 2 - • 31 January 2007 <br /> between 7 and 117 ug/kg. Delta-benzene hexachloride was found in the two-foot soil <br /> sample of SB-13 at concentration of 47 ug/kg. These compounds were not found at <br /> deeper intervals, were not found in groundwater, and are below the screening levels. <br /> Lead and zinc concentrations are much higher in the two-foot sample from SB-08 (550 <br /> mg/kg and 5,100 mg/kg, respectively), obtained near the railroad track to the north, than <br /> in the other soil samples. The elevated concentrations of lead and zinc were not <br /> present in the deeper soil sample, which was comparable in concentration to the other <br /> soil samples, which contained lead in concentrations from 3 to 24 mg/kg and contained <br /> zinc concentrations between 12 and 72 mg/kg. The lead and zinc concentrations found <br /> in soil are below the California Human Health Screening Levels (CHSSLs) for <br /> residential development. In groundwater, dissolved lead was not detected, and <br /> dissolved zinc ranged from 16 to 200 ug/I. These concentrations are below the <br /> screening levels and water quality objectives. <br /> Since the detections of chlorinated herbicides, organophosphate pesticides, <br /> organochlorine pesticides, lead, and zinc are either not detected, or detected below <br /> human health thresholds, or are only present in the shallow soil and do not present a <br /> threat to groundwater, Regional Water Board staff concur with the Investigation <br /> Report's conclusion that these compounds are not constituents of concern. <br /> Nickel is found in soil between 7 and 35 mg/kg, which is below the CHSSLs screening <br /> level of 16,000 mg/kg, but is found in groundwater in concentrations ranging from 18.to <br /> 180 ug/I. The water quality objective for nickel in groundwater is 12 ug/I, based on the <br /> Public Health Goal. <br /> Nitrate, ammonium, sulfate, and fuel <br /> Nitrate (as nitrogen) concentrations in soil range from 3 to 190 mg/kg, and ammonium <br /> ranges from 5 to 160 mg/kg. Since groundwater is less than 10 feet below ground <br /> surface, Regional Water Board staff assign a generic cleanup goal of 100 mg/kg for the <br /> sum of nitrate and ammonium in soil. This cleanup goal is a conservative estimate of <br /> the amount of nitrogen that could remain in soil and not migrate to groundwater. If <br /> Lesco believes that this is overly conservative, it may perform leachability tests on site <br /> soils to develop a site-specific cleanup level for nitrate and ammonium that is protective . <br /> of groundwater. To run the leachability test, at least five soil samples of varying <br /> concentrations of nitrogen should be split into two for two parallel analyses: one for <br /> total nitrate and ammonium, and one for leachable nitrate and ammonium. Leachable <br /> nitrogen is determined with the Waste Extraction Test modified using deionized water <br /> as the extractant. The extractionprocedure and the method for calculating the <br /> leachable fraction is described in the Designated Level Methodology for Waste <br /> Classification and Cleanup Level Determination (available at http://www.waterboards. <br /> ca.gov/centralvalley/available_documents/guidance/dlm.pdf). At the Lesco facility, <br /> there is not a good correlation between nitrate and ammonium concentrations in soil <br /> and those found in groundwater. <br /> The highest concentrations of nitrate and/or ammonium (above 300 mg/I as nitrogen) in <br /> groundwater occur in borings SB-11, SB-12, SB-13, and SB-15. Groundwater from <br /> these borings also contain 500-700 mg/I sulfate. Of these borings, SB-11, SB-12, and <br /> SB-13 are nearest a former unlined on-site stormwater pond (West Pond) that was <br />