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02 May 2013 <br /> AGE-NC Project No. 04-1168 <br /> Page 8 of 10 <br /> The estimated extent of dissolved TPH-g is depicted in Figure 6, and is representative of <br /> current groundwater conditions at the site. Based on the data, the dissolved extent can be <br /> separated into two contoured zones of 1,000 pg/I and 100 pg/I (i.e near non detect). The <br /> volume of each contour zones can be determined by utilizing the formula for an elliptical <br /> cylinder. Based on the estimated volumes of the above two contoured zone,the estimated <br /> volume of TPH-g impacted groundwater is approximately 0.35 pounds,equivalent to 0.056 <br /> gallons. Maximum dissolved mass-volume calculations are included in Appendix E. <br /> /6.0. RISK ASSESSMENT - SOIL VAPOR INTRUSION EVALUATION <br /> A soil vapor intrusion investigation has not been performed at the site. AGE believes that <br /> residual soil contamination left in p ace will not pose a significant threat to human health <br /> or to the environment based on the following: <br /> • Petroleum hydr=(Bl), <br /> soi wasencountered on ow the former USTs <br /> at depth 2 (B2,MW-1) and 45 feet bsg (B2). nzene was not <br /> detected in acted during the 2004 and 2005 ' estigations. <br /> • Although soil samples have not been laboratory analyzed from five and ten feet bsg, <br /> field samples at borings B1 and MW-1 had no observable hydrocarbon odor or <br /> positive photoionization detector (PID) readings (Table 1, Appendix C). <br /> • Based on the location and depths of residual impact hydrocarbon impact and the <br /> lateral distance from the site building (18 feet), it is not likely that vapor emitted from <br /> the plume would impact the on-site building (Figure 5). <br /> 7.0. DISCUSSION AND CONCLUSIONS <br /> Based on data collected during site assessment and groundwater monitoring events at the <br /> Arroyo's Smog Shop site, AGE concludes: <br /> • An unauthorized release of petroleum hydrocarbons has impacted soil beneath the <br /> formerly installed underground storage tanks. Once released to the subsurface,the <br /> petroleum hydrocarbon contaminants migrated vertically into the underlying silt and <br /> clay units to depths between 15 feet (bottom of former USTs) and 45 feet bsg. <br /> • The site is generally composed of alternating layers of silt and clay with intermittent <br /> small lenses of silty sand ( Appendix C and Figure 3). <br /> • The greatest adsorbed hydrocarbon concentrations were encountered within the <br /> former tank pit area near borings B1 and MW-1. Utilizing B1 as a mid-point, the <br /> Advanced GeoEnvironmental,Inc. <br />