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quarter 2006 and TCE was last detected in this well in 3`d quarter 2007. These are sporadic low <br /> concentration VOC detections that are generally not persistent at the well. <br /> 5 Year COCs <br /> Groundwater samples were analyzed for the Five-year Constituent of Concern this semester during <br /> the 3`d Quarter 2009. Results were unremarkable with one exception. Eight Semivolatile Organic <br /> Compounds(SVOCs)were observed in both MW-3 and background well MW-4. When retested <br /> during the 4th Quarter 2009 sampling event, these SVOCs were not observed in either MW-3 or <br /> MW-4, which indicates that the first reports were erroneous, probably due to laboratory <br /> contamination. None of the other 5-year COC monitoring parameters suggested that the water <br /> from the monitoring wells had been impacted by landfill activities. <br /> Surface Water <br /> Surface water samples were taken from the creek flowing along the eastern perimeter of the <br /> property during the first semester 2009. The results of analyses of the upstream and downstream <br /> samples were similar. The downstream sample was less in both total dissolved solids and <br /> electrical conductivity than the upstream sample, indicating that the landfill did not contribute to <br /> the surface water in these respects. No surface water samples were collected during the second <br /> semester due to lack of flowing water. <br /> Note that the creek receives contribution from the ground surface and several smaller creeks on <br /> the property east of the creek, and that these surfaces and the creek itself are subject to cattle <br /> grazing. The County and landfill operator cannot control constituents that may be carried into the <br /> creek from the other property. <br /> Leachate <br /> Waste Discharge Requirements require monitoring leachate flow rate, pH, and Electrical <br /> Conductivity on a monthly basis (Table 5). Leachate volumetric data for several months indicates <br /> reasonable average flow rates. <br /> Vadose Zone Soil Gas <br /> First Semester Results <br /> Soil gasses were sampled on July 15, 2009. Samples were collected by first measuring the <br /> methane content using a CES-LANDTEC GEMTM 500 portable gas analyzer. The GEMTM 500 <br /> was operated until a steady-state gas composition indicated that the well was purged. After <br /> purging, gas samples were collected in stainless steel Summa canisters and sent to Atmospheric <br /> Analysis &Consulting, Inc. for analysis by EPA method TO-14A (Appendix I). <br /> Second Semester Results <br /> VOCs were detected in all soil gas samples (Table 6). The highest concentration of any VOC was <br /> found in SG-l. Freon 12 was most often reported with the highest concentration in a sample. The <br /> Foothill Sanitary Landfill 9 Department of Public Works/Solid Waste <br /> 2'a Semester and Annual 2009 Groundwater Monitoring County of San Joaquin—January 31,2010 <br />