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sample indicate that there were no new COCs detected above the PQL, and as a result, <br /> verification testing is not required. <br /> 2.1.7 Surface Water Monitoring <br /> Site run-on and run-off control facilities are designed to effectively channel surface water <br /> to site stormwater/sedimentation ponds. According to the Operations Manager, there <br /> were no discharges to surface water during the reporting quarter. During the fourth <br /> quarter 2010 monitoring period, surface-water monitoring stations FSW-I and FSW-2 <br /> were sampled on December 27, 2010. Table 2-7 summarizes the current analytical <br /> results for surface water samples collected at the Forward Unit. As shown on Table 2-7, <br /> no VOCs were detected in the samples collected from the surface water stations during <br /> the fourth quarter 2010 monitoring period. A comparison of upgradient(FSW-2)to <br /> downgradient(FSW-1) surface water samples indicates generally similar concentrations <br /> suggesting that the landfill operations are not impacting surface water quality. <br /> 2.2 SUMMARY <br /> Groundwater quality conditions beneath the Forward Unit during the fourth quarter 2010 <br /> monitoring period are generally similar to those observed in previous monitoring periods. <br /> During the fourth quarter 2010 monitoring period, 17 new historical intrawell maximum <br /> values were measured in samples collected from groundwater monitoring wells, <br /> including eight first-time VOC detections. The organic results for the Forward Unit <br /> indicate that the following VOCs were measured above their respective PQLs, acetone <br /> and MEK in the samples collected from upgradient(background)wells MW-2A and <br /> MW-17; and cis-1,2-DCE, PCE, and TCE in the samples collected from wells MW-22 <br /> and MW-23R. In addition, PCE was measured at an estimated trace concentration in the <br /> sample collected from well MW-14. CLs were exceeded for one or more monitoring <br /> parameters in samples from seven wells. In accordance with the RPCMP, inorganic <br /> exceedances of CLs that are potential impact constituents (potassium at well MW-18, and <br /> chloride at well MW-22) will be resampled in February 2011 (during the first quarter <br /> 2011 sampling event), and a second independent sample will be collected in March 2011. <br /> The results of the two retests will be submitted to DTSC and RWQCB under separate <br /> cover. <br /> The fourth quarter 2010 leachate monitoring results are generally similar to those <br /> observed historically. During the monitoring period, 13 dissolved metal constituents <br /> were measured with eight above their PQL; three VOCs were measured above their PQL; <br /> eight semi-volatile organic compounds(SVOCs) were measured with three above their <br /> PQL; and one herbicide was measured above its PQL in the leachate sample collected <br /> during the fourth quarter 2010 monitoring period. No pesticides were detected in the <br /> leachate sample. The results of the annual leachate sample indicate that there were no <br /> new COCl detected. <br /> During the October and November 2010 inspections,the CEHD measured methane <br /> concentrations exceeded the regulatory limit of five percent in perimeter soil-pore gas <br /> D:X2010_0013TA_4Q10.doc 8 Geologic Associates <br />