ARCHIVED REPORTS_2011_26 - Laserfiche WebLink

Home Browse Search

The guidance also states that a minimum of ten sources should be used in developing a default value(use of fewer sources results in unreliable values).However several of the AP-42 defaults were developed from many fewer samples and sometimes just one sample.In view of the high variability observed between landfill test results,it is recommended that U.S.EPA carefully review its practices in developing AP-42 defaults with fewer than ten samples.At a minimum, defaults derived from limited data should be clearly identified and users cautioned as to their questionable reliability. LFG Constituent Declines Large,long term declines in LFG HAP values were documented in the August 1999 WIAC report.This report focused on four active and two closed landfills in Southern California.The decline at the active landfills was concurrent with implementation of waste-screening programs that prevented the disposal of incidental amounts of hazardous wastes present in the municipal solid waste stream starting in the early 1980's.U.S.EPA's Resource Conservation and Recovery Act(RCRA)rules for MSW landfills,implemented starting October 9, 1991 (40 CFR 258.20) also began requiring such exclusion programs on a nationwide basis.Additionally,the U.S.EPA established Subtitle C requirements per the 1984 RCRA amendments that set minimum treatment standards for listed wastes.This program ensured that the treatment residuals were placed in Subtitle C landfills.The combination of these programs likely reduced or eliminated incidental hazardous waste disposal in active MSW landfills. An attempt was made to determine whether a similar long term decline could be detected at other active landfills represented in the AP-42 database.A comparison was made of those sites that were reported by both EPA and WIAC.However it was found that many of the AP-42 landfills had coded names.The only active sites identifiably the same were those already'reported in the August 1999 report.It is recommended that U.S.EPA identify the coded AP-42 landfills so that a meaningful comparison could be made with the WIAC results. The LFG HAP decline for the two closed landfills in the August 1999 report would be unrelated to improved hazardous waste management practices.However the anaerobic decomposition processes at these sites are likely to have brought about such declines through one or more mechanism.HAP compounds will tend to volatilize into newly generated anaerobic gases;the .gases together with the trace constituents will ultimately exit the landfill,removing the HAP compounds.Additionally,anaerobic processes may destroy or transform some HAP compounds. Another factor to consider in the decline of HAP compounds is the effect of improved laboratory methodologies in recent years.Areas of improvement include utilization of more sophisticated equipment and adoption of standardized procedures for all analytical aspects.Some of the improved procedures include sample container preparation,instrument calibration,and quality assurance acceptance criteria. Equipment and procedure improvements reduce the scatter of data,increase data reliability, minimize compound misidentifications,and lower detection limits.Detection limits are especially important since several of the AP-42 compounds have few or no detections;improved detection limits would tend to lower the calculated AP-42 defaults.One laboratory submitting data for this report indicated that detection limits were more than halved in the last five years. Urban Air Toxics Strategy The U.S.EPA used AP-42 defaults for the recently completed Urban Air Toxics(UAT)Strategy. A review of the UAT findings based on the newer WIAC results is presented in Table 3.For all compounds detected in LFG,municipal landfills dropped in rank among industrial sources.The 6