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AMW-14; hexavalent chromium at AM -14; magnesium at AMW-6, AMW-7, and AMW-14; <br />nitrate at W-2, AMW-6, AMW-7, and AMW-14; field pH at AMW-6; potassium at AMW- <br />14; sodium at AMW-14; field specific conductance at AMW-2, AMW-6, and AMW-7; strontium <br />at W-6 and AMW-14; sulfate at AMW-7, AMW-13, AMW-14; TDS at AMW-6 and AMW- <br />7; and field turbidity at AMW-12. Carbonate at AMW-2 exhibited an apparent increasing trend <br />according to the Mann -Kendall / Sen's Slope analysis, but this trend is due to a historical increase <br />in the laboratory RL. <br />Given that bicarbonate alkalinity, nitrate, and field specific conductance exhibit significant <br />increasing trends at upgradient well AMW-2, the increasing trends for these constituents at <br />downgradient wells are likely due to ongoing changes in the natural groundwater geochemistry at <br />the site. <br />Mann -Kendall / Sen's Slope analysis identified significant decreasing statistical trends for the <br />following inorganic constituents: calcium at AMW-12, chloride at AMW-12 and AMW-13, <br />hexavalent chromium at AMW-7, nitrate at AMW-13, potassium at AMW-7, strontium at AMW- <br />12, and field turbidity at AMW-2. <br />Mann -Kendall / Sen's Slope analysis did not identify any significant increasing statistical trends <br />for VOCs. Mann -Kendall / Sen's Slope analysis identified significant decreasing statistical <br />trends for 1,1-dichloroethane at AMW-13, dichlorodifluoromethane at AMW-14, <br />tetrachloroethene at AMW-14, and trichloroethene at AMW-14. <br />The third quarter 2012 barium concentration at AMW-12 (0.28 mg/L) is within the range of <br />concentrations observed at that well since the beginning of monitoring in May 1995 (0.14 to 0.28 <br />mg/L). As discussed above, barium at AMW-12 does not exhibit a significant increasing <br />statistical trend. A Wilcoxon rank -sum test comparing the barium data at upgradient well AMW- <br />2 to the data at AMW-12 (a = 0.05) indicates that the barium data at AMW-12 are statistically <br />distinct from those at the upgradient well. The Wilcoxon rank sum plot is presented in Appendix <br />E. The presence of stable barium concentrations at AMW-12 that are statistically distinct from <br />upgradient concentrations indicates that the concentration limit exceedance for barium at AMW- <br />12 in the third quarter 2012 is likely due to spatial variation in the natural groundwater <br />geochemistry at the site. <br />The third quarter 2012 barium concentration at AMW-13 (0.28 mg/L) is within the range of <br />concentrations observed at that well since the beginning of monitoring in May 1995 (0.24 to 0.34 <br />mg/L). As discussed above, barium at AMW-13 does not exhibit a significant increasing <br />statistical trend. A Wilcoxon rank -sum test comparing the barium data at upgradient well AMW- <br />2 to the data at AMW-13 (a = 0.05) indicates that the barium data at AMW-13 are statistically <br />distinct from those at the upgradient well. The Wilcoxon rank sum plot is presented in Appendix <br />E. The presence of stable barium concentrations at AMW-13 that are statistically distinct from <br />upgradient concentrations indicates that the concentration limit exceedance for barium at AMW- <br />13 in the third quarter 2012 is likely due to spatial variation in the natural groundwater <br />geochemistry at the site. <br />The third quarter 2012 barium concentration at AMW-14 (0.29 mg/L) is within the range of <br />concentrations observed at that well since the beginning of monitoring in July 1995 (0.093 to 0.3 <br />mg/L). As discussed above, barium at AMW-14 exhibits a significant increasing statistical trend. <br />The increasing trend is not observed when the data are limited to the period of November 2009 to . <br />August 2012. A Wilcoxon rank -sum test comparing the July 1995 to August 2009 barium data at <br />AMW-14 to the November 2009 to August 2012 data (a = 0.05) indicates that these periods are <br />