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monitoring station were sampled by Del-Tech Environmental Support Services(Del- <br /> Tech) on November 27, and December 4, 2012. The lysimeters were checked for soil- <br /> pore liquid on November 28, 2012, and Del-Tech reported that all lysimeters were dry. <br /> Of note,there was no access port to inspect pan lysimeters WMW-DOIN, WMW-DOIS, <br /> and WMW-D02. <br /> Samples were collected by Del-Tech from each sample point containing sufficient liquid <br /> and submitted to BC Laboratories (BC) of Bakersfield, California, a state certified <br /> laboratory under contract to Forward. During the fourth quarter 2012 monitoring period, <br /> samples were analyzed for the routine monitoring parameters stipulated in RWQCB <br /> Order No. R5-2003-0049. Table 2-1 summarizes site monitoring parameters, analytical <br /> methods, and monitoring frequency. Water quality samples were also analyzed in the <br /> field for oxidation-reduction potential (ORP),turbidity, temperature, specific <br /> conductance, and pH and recorded on well data sheets. The groundwater monitoring <br /> wells and leachate monitoring points were sampled in accordance with the sampling and <br /> analysis procedures detailed in Appendix B. The well data sheets, laboratory data, <br /> certificates of analyses, and chain-of-custody records for the sampling program are <br /> included in Appendix C. The laboratory analyses and field results for groundwater <br /> monitoring wells, surface water stations, lysieter, and leachate sampling stations are <br /> summarized in Tables 2-2 through 2-7. <br /> QA/QC Results <br /> The quality assurance/quality control (QA/QC) program completed for the fourth quarter <br /> 2012 water quality monitoring event included analyses of two trip blanks, four laboratory <br /> method blanks, and one duplicate sample. The trip blanks were analyzed for volatile <br /> organic compounds (VOCs) by EPA Method 8260 and method blanks were analyzed for <br /> all of the analytes included in the monitoring program. The results of the QA/QC <br /> program indicate that no VOCs were detected in trip or method blanks during the <br /> monitoring period. Inorganic constituents including chloride, hexavalent chromium, <br /> arsenic, magnesium, iron,manganese, and tin were measured at trace concentrations in <br /> method blanks analyzed with groundwater and leachate samples. These constituents <br /> were measured at very low concentrations that generally did not affect the interpretation <br /> of primary sample results. However, since hexavalent chromium is only detected <br /> intermittently in groundwater samples, it was flagged as a laboratory contaminant on <br /> Table 2-2 when the primary sample results were measured at an estimated, trace <br /> concentration. A duplicate sample was collected from well MW-22 and labeled FMW- <br /> Duplicate. With the exception of arsenic and nitrate (as N), which had relative percent <br /> differences (RPD) of 23 percent and 14 percent(respectively), the duplicate sample <br /> analyses yielded good correlation with a RPD of seven percent or less. The larger RPD <br /> between the primary and duplicate sample may be associated with the detection of <br /> arsenic in the method blank that was analyzed with these samples. Review of the <br /> sampling dates and laboratory analytical certificates indicates that all of the laboratory <br /> analyses were completed within required holding times. Based on the results of the <br /> laboratory QA/QC analyses, it is concluded that the laboratory data generated for the <br /> fourth quarter 2012 monitoring period are generally acceptable and the water quality <br /> C:\2012-0025\FA4Q12.doc 4 Geo-Logic /Associates <br />