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2016 Corrective Action Evaluation Report - Austin Road Unit <br />Forward Landfill <br />The TVOC mass between each pair of isoconcentration contours was first estimated by <br />multiplying the average TVOC concentration between those contours by the assumed <br />aquifer thickness and porosity. (For example, the average TVOC concentration between <br />the 25 µg/L and 50 µg/L contours would be 37.5 µg/L.) Consistent with the Evaluation <br />Procedures Report, the aquifer thickness was assumed to be 40 feet and the aquifer <br />porosity was assumed to be 0.25. <br />The TVOC masses corresponding to all contour pairs on a given quarter's isoconcentration <br />map were then summed to estimate the total, plume -wide TVOC mass for that quarter. <br />Tables 6 through 9 summarize the quarterly TVOC mass estimation calculations for the <br />monitoring period; the historical TVOC masses for the facility are summarized on Table 11; and <br />the corresponding quarterly groundwater potentiometric maps are presented in Appendix A. <br />The TVOC mass for each quarter was compared to the TVOC mass TL of 789.5 kg. During the <br />monitoring period, the calculated quarterly TVOC mass did not exceed the TL. <br />2.0 TVOC MASS TREND <br />The estimated TVOC masses for the past four quarters were reviewed for increasing trends. <br />TVOC mass has not increased for four consecutive quarters at any time in the past year. As <br />discussed in Section 1.0, the TVOC mass calculations performed for this monitoring period also <br />included the 18 EMP/CAP wells that were not included in previous annual reports. As a result, <br />the quarterly TVOC mass calculations summarized in Table 11 are significantly greater than in <br />previous Annual Corrective Action Evaluation Reports. In order to evaluate if any significant <br />change has occurred in the TVOC concentrations and/or TVOC mass, analytical data from the <br />second quarter 2014 using the additional 18 EMP/CAP wells, was compared to the results <br />calculated during the current monitoring period. A comparison of the isoconcentration map for <br />groundwater TVOC concentrations during the second quarter 2014 (Figure 5) with the current <br />results (Figures 1 through 4) depicts a similar VOC plume geometry, and the TVOC mass <br />calculation of 196.3 kg (Table 10) is within the range of values calculated during the current <br />monitoring period (Table 11). Of note, the second quarter 2014 was the first monitoring event <br />that the additional 18 EMP/CAP wells were sampled. <br />3.0 INDIVIDUAL WELL TVOC CONCENTRATIONS <br />The TVOC concentrations observed at individual wells for the past four quarters are presented <br />on Tables 2 through 5 and summarized on Table 12. A time series charts for TVOC mass and <br />individual well TVOC concentrations, and a historical database summary are presented in <br />Appendix B. <br />The individual TVOC concentrations for each quarter were compared to the established TVOC <br />concentration TLs. As shown on Table 12, there were four individual well TL exceedances during <br />® Project No. 2016.0007 12016 Corrective Action Evaluation Report - Austin Road Unit 3 <br />Forward Landfill <br />