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2.0 Groundwater Monitoring Program <br />During the third quarter 2011 monitoring event, groundwater monitoring was performed at the <br />French Camp Landfill by Del -Tech. Groundwater samples were collected from two background <br />monitoring wells (MW -6A and MW -7A) and four detection monitoring wells (MW -8A, MW -9A, <br />MW -9B, and MW-l0A) during the third quarter 2011 monitoring event. The analytical results <br />from samples collected at these wells are used to determine potential landfill -related impacts. <br />The WDRs stipulate semi-annual sampling of the background monitoring wells and detection <br />monitoring wells for field parameters (pH, specific conductance, temperature, and turbidity) and <br />monitoring parameters (bicarbonate, calcium, carbonate, chloride, magnesium, nitrate, potassium, <br />sodium, sulfate, TDS, and VOCs). <br />The field results provided by Del -Tech and the laboratory results provided by BC Labs for the <br />third quarter 2011 groundwater monitoring event are summarized on Table 2.2. The historical <br />groundwater data for the background and detection monitoring wells are presented in Appendix <br />D. Times series concentration plots of historical groundwater data for the monitoring wells are <br />presented in Appendix E. The concentration limits presented on Table 2.2 were calculated from <br />background data collected through the third quarter 2011 monitoring event. The statistical <br />analysis calculations for groundwater monitoring wells are presented in Appendix E. A copy of <br />the statistical analysis methodology is presented in Appendix C. <br />As presented on Table 2.2, the following constituents exceeded their respective concentration <br />limits during the third quarter 2011 event: calcium at MW -9B; and field temperature at MW -9A, <br />MW -9B, and MW -10A. There were two VOCs detected at groundwater monitoring wells during <br />the third quarter 2011 event. Chloroform was detected at upgradient well MW -6A at a <br />concentration of 1.2 ug/L, and trichlorofluoromethane was detected at downgradient well MW - <br />9A at a concentration of 0.53 ug/L. <br />Historical data from the groundwater monitoring wells were analyzed for temporal trends using <br />Mann -Kendall / Sen's Slope trend analysis. Graphs and summary tables of the Mann -Kendall / <br />Sen's Slope analyses for groundwater monitoring wells are presented in Appendix E. <br />Chloride at MW -10A, potassium at MW -9B, sulfate at MW -913, and field temperature at MW -8A <br />exhibited significant increasing statistical trends. None of these constituents exceeded their <br />concentration limits. Mann -Kendall / Sen's Slope analysis identified significant decreasing <br />statistical trends in the following constituents: bicarbonate alkalinity at MW -8A; calcium at MW - <br />6A and MW -8A; chloride at MW -7A and MW -8A; magnesium at MW -6A and MW -8A; nitrate <br />at MW -8A, MW -9A, and MW -10A; field pH at MW -6A and MW -9B; field specific conductance <br />at MW -7A; TDS at MW -7A and MW -8A; trichlorofluoromethane at MW -9A; and field turbidity <br />at MW -7A. Given that field pH exhibits a significant decreasing statistical trend at upgradient <br />well MW -6A, the decreasing trend for field pH at downgradient well MW -913 is likely due to <br />ongoing changes in the natural groundwater geochemistry at the site. <br />The third quarter 2011 calcium concentration at well MW -9B (130 mg/L) is within the range of <br />concentrations observed at MW -913 since the beginning of background in May 2005 (109 mg/L — <br />180 mg/L). As discussed above, calcium at MW -913 does not exhibit a significant upward <br />statistical trend. A Wilcoxon rank -sum test comparing the calcium data at background wells <br />MW -6A and MW -7A to the data at MW -913 (a = 0.05) indicates that the calcium data at MW -913 <br />are statistically distinct from those at the background wells. The Wilcoxon rank sum plot is <br />presented in Appendix E. The presence of stable calcium concentrations at MW -9B that are <br />statistically distinct from background indicates that the concentration limit exceedance for <br />