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STANDARD PROVISIONS AND REPORTING REQUIREMENTS,JANUARY 2012 -22- <br /> FOR WASTE DISCHARGE REQUIREMENTS <br /> FOR DISCHARGES REGULATED BY SUBTITLE D AND/OR TITLE 27 <br /> be taken as the detection limit of the analytical method used (e.g., USEPA <br /> methods 8260 and 8270). <br /> 44.Alternate statistical procedures may be used for determining the significance of <br /> analytical results for common laboratory contaminants (i.e., methylene chloride, <br /> acetone, diethylhexyl phthalate, and di-n-octyl phthalate) if part of an approved <br /> water quality protection standard. Nevertheless, analytical results involving <br /> detection of these analytes in any background or downgradient sample shall be <br /> reported and flagged for easy reference by Central Valley Water Board staff. <br /> 45.Confirmation of Measurably Significant Evidence of a Release. Whenever <br /> a constituent is detected at a detection monitoring point at a concentration that <br /> exceeds the concentration limit from the water quality protection standard, the <br /> Discharger shall conduct verification sampling to confirm if the exceedance is <br /> due to a release or if it is a false-positive (unless previous monitoring has <br /> already confirmed a release for that constituent at that monitoring point). An <br /> exceedance of the concentration limit from the water quality protection standard <br /> is considered measurably significant evidence of a release that must be either <br /> confirmed or denied. There are two separate verification testing procedures: <br /> a. Standard Monitoring Specification 1.46 provides the procedure for analytes <br /> that are detected in less than 10% of the background samples such as non- <br /> naturally occurring constituents like volatile organic compounds; and <br /> b. Standard Monitoring Specification 1.47 provides the procedure for analytes <br /> that are detected in 10% or greater of the background samples such as <br /> naturally occurring constituents like chloride. <br /> 46.Verification Procedure for Analytes Detected in Less than 10% of <br /> Background Samples. The Discharger shall use the following non-statistical <br /> method for all analytes that are detected in less than 10% of the background <br /> samples. The non-statistical method shall be implemented as follows: <br /> a. Initial Determination of Measurably Significant Evidence of a Release. <br /> Identify each analyte in the current detection monitoring point sample that <br /> exceeds either its respective MDL or PQL, and for which a release has not <br /> been previously confirmed. The Discharger shall conclude that the <br /> exceedance provides a preliminary indication of a release or a change in the <br /> nature or extent of the release, at that monitoring point, if either: <br /> 1) The data contains two or more analytes that equal or exceed their <br /> respective MDLs; or <br /> is 2) The data contains one or more analyte that equals or exceeds its PQL. <br />