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RECEIVED
<br /> rLU n 6 2020
<br /> Table 164 : Individual Analytes and Methods for Soil and Groundwater Sa I 1XIat i UTAL HEALTH
<br /> Source Fuel / Product Analytical
<br /> Type Analytes Method (s) Comments
<br /> Gasoline BTEX, naphthalene, EPA 8260B/C organic lead ( GC- ECD )
<br /> MTBE, TBA
<br /> ( plus EDC, EDB for pre- 1992 release ) ' only ifpre- 1992
<br /> is present
<br /> Jet A/JP5/J P8, Diesel # 1 BTEX, naphthalene, MTBE EPA 8260B/C MTBE3
<br /> or #2, Fuel oil # 1 or #2
<br /> BTEX, MTBE, EPA 8260B/C MTBE3
<br /> naphthalene
<br /> Heavy Fuel Oils ( bunker
<br /> fuel, etc. )
<br /> 16 priority pollutant PAH S2 EPA 8270 SIM
<br /> BTEX, naphthalene, chlorinated VOCs, EPA 8260B/C
<br /> MTBE, TBA
<br /> Waste ( Used ) Motor Oil 16 priority pollutant PAHs2 EPA 8270 SIM
<br /> Wear Metals : cadmium, chromium, EPA 6010/6020 or Soil only
<br /> nickel, lead, zinc EPA 7000/7010
<br /> Notes :
<br /> BTEX Benzene, toluene, ethylbenzene, and xylene
<br /> EDB 1, 2-dibromoethane
<br /> EDC 1, 2-dichloroethane
<br /> Jet A Commercial jet fuel
<br /> JP5 Jet Propellant 5, military jet fuel
<br /> JP8 Jet Propellant 8, military jet fuel
<br /> MTBE Methyl tertiary butyl ether
<br /> PAH Polycyclic aromatic hydrocarbon
<br /> TBA t- Butyl alcohol
<br /> VOC Volatile organic compound
<br /> 1 ) Samples to be analyzed for lead scavengers EDC and EDB only if release is pre - 1992 . If age of release is
<br /> unknown , analyze for both oxygenates ( MTBE and TBA) and scavengers .
<br /> 2 ) 16 priority pollutant PAHs = naphthalene, acenaphthene, acenaphthylene, anthracene, phenanthrene,
<br /> fluorene, chrysene, fluoranthene, pyrene, benzo ( b )fluoranthene, benzo ( a ) pyrene, benzo ( k)fluoranthene, ,a
<br /> benzo ( a ) anthracene, indeno ( 1, 2, 3 -c, d ) pyrene, dibenz ( a , h ) anthracene, benzo (g, h, i ) perylene . o
<br /> 3 ) MTBE to be analyzed at all LUFT sites unless regulatory agency has determined that the tank contained only
<br /> diesel or jet fuel per California Health & Safety Code ( H &SC) § 25296 . 15 ( a ) .
<br /> Background Regarding Total Petroleum Hydrocarbon (TPH) Analyses
<br /> Cc
<br /> California and other states have had different approaches to analytical requirements for the bulk or "total" '
<br /> petroleum mixture at LUFT sites . In the 1980s, the gravimetric analysis "total oil and grease" (TOG; EPA Method
<br /> 413 ) was replaced by "total recoverable petroleum hydrocarbons" (TRPH ; EPA Method 418 . 1) because EPA d
<br /> Method 418 . 1 included a silica gel cleanup ( SGC) and was therefore more specific to hydrocarbons . In the early
<br /> 1990s, the TRPH analysis ( EPA Method 418 . 1) was replaced for LUFT site characterization by EPA Method 8015
<br /> ( purgeable and extractable "total petroleum hydrocarbons" or TPH ) , performed using GC- FID . EPA Method 8015 is
<br /> an aggregate analysis that quantifies the total amount of organic compounds present in a sample over a selected ,0
<br /> carbon range ( boiling point range) . Petroleum hydrocarbons may, or may not, be present in the sample because
<br /> California LOFT Manual: September 2012 16 -4
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