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PANOCHE BURN SITE REMEDIATION <br /> The ash was dry and hydrophobic, and moisture-conditioning was difficult. To prevent <br /> fugitive dust and hazardous air emission from the lead and zinc, two 4,000-gallon water <br /> trucks were used. <br /> 3.2.4 Stained Material <br /> On the north slope below the rock outcrop and two areas along the south slope, black staining <br /> was observed 4 to 5 feet below the ash layer. Black staining was along the side slopes in the <br /> natural clay soils. The stained soil did not have an odor, was more pronounced toward the <br /> bottom, occurred in random elevations, and did not contain ash residue or elevated levels of <br /> zinc. After reviewing the laboratory results (See Section 3.4.4) and site conditions, the <br /> CIWMB engineer concluded the black stained soil was probably due to the pyrolysis of the <br /> oil in the soil column. As the tire fire burned, large quantities of pyrolytic oil were released <br /> and saturated the soil column below. With the extreme temperatures from the fire from below <br /> the canyon rim and above, the pyrolytic oil on the side slopes presumably chemically <br /> decomposed, leaving only carbon black (i.e., tire filler). <br /> 3.2.5 Pyrolytic Oil Contamination <br /> Initially, all or most of the pyrolytic oil was assumed to have been consumed during the tire <br /> fire. However, the CIWMB investigation showed the oil was 30 to 40 feet below the original <br /> surface, 50 to 100 feet long, and 25 to 30 feet wide. After examining the removed soil at the <br /> bottom of the retention basin, the CIWMB engineer determined the pyrolytic oil from the tire <br /> fire permeated through a gravel lens in the upper part of the canyon and traveled downward <br /> toward the creek. The lens acted as a conduit allowing the pyrolytic oil to advance and bypass <br /> the above clay layers. Because the oil stain migrated along a gravel lens down the canyon, the <br /> CIWMB engineer directed Sukut to perform exploratory trenching to locate the extent and <br /> depth of the contamination. To define the area of concern, the old check dam was removed. <br /> Figure 5 shows the excavated area of pyrolytic oil. The cut slope along the northern <br /> embankment showed the gravel lens containing the oil. See the photo log in Appendix G for <br /> further details. <br /> Trenching indicated the oil migrated under the majority of the old check dam and ended at a <br /> natural clay barrier in front of the new retention dam. The natural barrier prevented the oil <br /> from contaminating Little Panoche Creek. Figure 6 shows the general path of the pyrolytic <br /> oil. To reduce the possibility of the oil contaminating the surface water within the basin, the <br /> CIWMB engineer elected to remove as much of the stained soil as feasible. When the <br /> excavation was stopped, pyrolytic oil was observed in a gravel lens located at the bottom of <br /> both slopes and at the toe of the fill. The excavated material was placed in the upper region <br /> of the fill on top of the ash and then capped with soil. Based on actual scraper counts, a total <br /> of 5,600 cubic yards of oil-contaminated soil was placed on top of the fill area under the <br /> foundation layer. <br /> Unfortunately, not all of the pyrolytic oil material could be safely removed. Removing all the <br /> contaminated gravel would have required a massive construction effort. First, the entire <br /> CIWMB 17 <br />