• During the first quarter 2006, TBA, DIPS, ETBE, TAME, EDB, or ethanol were not reported in any of the
<br /> upper zone ARCO wells GRO (640 �Lg/L) and benzene (5 5 pg/L) were reported in well MW-4 MTBE
<br /> was reported in wells MW-1, MW-3 through MW-6, MW-8, MW-11, and MW-13, at concentrations ranging
<br /> from 0 80 µg/L (MW-3) to 5,700 µg& (MW-6) 1,2-DCA was reported in wells MW-7 (1 0 Pg1L), MW-12
<br /> (0 74 µg/L), and MW-13 (7 4 pg/L) GRO, benzene, and MTBE analytical data for the first quarter 2006
<br /> are presented in Figure 5 Analytical data were submitted to the State Water Resources Control Board as
<br /> required by AB2886 The electronic delivery receipt is attached in Appendix C Historical groundwater
<br /> monitoring and chemical analytical data (2000-2004) are included in Appendix D
<br /> Lower Zone Wells
<br /> At the time of the first quarter 2006 monitoring event, groundwater had increased 1 22 and 1 60 feet in
<br /> wells MW-9 and MW-10, respectively, since the previous monitoring event (December 8, 2005) Depth to
<br /> water measurements were corrected to mean sea level (MSL) and used to construct a groundwater
<br /> elevation contour map (Figure 4) East-southeast groundwater flows, at average gradients ranging from
<br /> 0 0012 ft/ft offsite to 0 0093 ft/ft onsite, were generally observed
<br /> During the first quarter 2006, GRO, BTEX, TBA, ETBE, TAME, EDB, or ethanol were not reported in any
<br /> of the lower zone ARCO wells MTBE was reported in wells MW-9 (8 4 pg/L) and MWA 0 (23 µg/L)
<br /> 1,2-DCA was reported in wells MW-9 (1 8 pg/L) and MW-10 (6 7 µg/L) DIPE (2 1 µg/L) was reported in
<br /> well MW-10 GRO, benzene, and MTBE analytical data for the first quarter 2006 are presented in Figure
<br /> 6 Analytical data were submitted to the State Water Resources Control Board as required by AB2886
<br /> The electronic delivery receipt is attached in Appendix C Historical groundwater monitoring and chemical
<br /> analytical data (2000-2004) are included in Appendix D
<br /> REMEDIATION SYSTEM STATUS
<br /> • System Description
<br /> The C-SpargeTM system, manufactured by KVA®, consists of a control panel (ozone generator, air
<br /> compressor, and tubing manifold), and injection points (IW-1 through IW-5, see Figure 2) used to inject
<br /> low concentrations of ozone into groundwater In addition, the control panel also has a programmable
<br /> timer that limits the amount of ozone injected into each injection point The system injects a timed pulse
<br /> of ozone at low flows and low pressures (10-30 psi) to each of the five injection points in a sequence The
<br /> ozone dissolved in groundwater is expected to oxidize petroleum hydrocarbons into carbon dioxide and
<br /> water, and any un-reacted ozone will degrade to dissolved oxygen, which is likely to enhance natural
<br /> biodegradation of residual petroleum hydrocarbons
<br /> System Operation Details
<br /> The C-Sparge m system was started on December 26, 2002 The C-SpargJm control panel was
<br /> programmed and scheduled to inject ozone cyclically into each injection point for 14 minutes Based on
<br /> this programming, each injection point will have ozone injection in 18 cycles for 4 2 hours every day The
<br /> bearings on the compressor appear to have worn out and a new compressor was installed on February 1,
<br /> 2006
<br /> During the first quarter 2006 (from January 10, 2006 to March 21, 2006), a Stratus technician conducted
<br /> six site visits to collect field and laboratory parameters, and to conduct operation and maintenance of the
<br /> ozone injection system Field data sheets presenting field parameters collected during the fourth quarter
<br /> 2005 are included in Appendix A Certified analytical reports with chain-of-custody documentation are
<br /> included in Appendix C Analytical data were submitted to the State Water Resources Control Board as
<br /> required by AB2886 The electronic delivery receipt is attached in Appendix C
<br /> K IBp-Arco for URS154691Quarteriy120061Arco_5469_1Q06 docPage 4 of 6 57"RA7"u5
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