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During second quarter 2003 (between March 24, 2003 and June 9, 2003), Stratus technician conducted <br /> seven site visits to troubleshoot the ozone injection system and collect field parameters and laboratory <br /> parameters. Field data sheets presenting field parameters collected between March 24, 2003 and June <br /> 9, 2003 are included in Appendix A, and certified analytical reports with chain-of-custody documentation <br /> are included in Appendix C. <br /> The C-SpargeTM system was non-operational between March 12, 2003 and April 3, 2003, and was <br /> restarted on April 3, 2003 after replacing a timer contact. In addition, other minor malfunctions (program <br /> controller) happened during second quarter 2003, resulting in relatively low uptime. Stratus also <br /> observed additional minor malfunctions during the second quarter 2003. Therefore the operational <br /> uptime period for C-SpargeTM system during second quarter 2003 was low. Stratus repaired the <br /> C-SpargeTM system program controller on June 26, 2003, and anticipates a higher operational uptime for <br /> the C-Sparge M system. <br /> Ozone infection Monitoring Plan <br /> Monitoring wells MW-3 through MW-10 are used as observation wells to monitor the performance of <br /> ozone injection system. Monitoring wells MW-1 and MW-2 are used as background wells to evaluate <br /> and monitor for natural geo-chemical changes in groundwater. The following field and laboratory <br /> parameters will be monitored periodically to evaluate and optimize the performance of the ozone <br /> injection system. <br /> Field Parameters (Bi-monthly): pH, Dissolved Oxygen (DO), and Specific Conductivity <br /> Laboratory Parameters (Quarterly): TPHG, BTEX, Chemical Oxygen Demand (COD), Ferrous Iron, Total <br /> Organic Carbon (TOC), DO, and Oxidation Reduction Potential <br /> (ORP) <br /> During second quarter 2003, field parameters were collected on a bi-monthly basis and laboratory <br /> parameters were collected on a quarterly basis. Table 3 presents the sampling frequency, field and <br /> laboratory parameters analyzed, and significance of both laboratory & field parameters. <br /> During the second quarter 2003 monitoring event, all samples were collected after purging three volumes <br /> of well casing. <br /> Results <br /> Results of field and analytical parameters collected to date to evaluate and optimize the performance of <br /> ozone injection system are presented in Tables 4 and 5. Due to low operational uptime of the <br /> C-SpargeTM system, no significant changes in DO levels and/or in petroleum hydrocarbon concentrations <br /> were observed during the second quarter 2003. The average DO levels at observation wells MW-7 and <br /> MW-9, both located approximately 15 feet from injection point IW-5, continue to be higher in comparison <br /> to the DO levels at background wells MW-1 and MW-2 (see Figure 4). <br /> Concentrations of petroleum hydrocarbons and/or fuel oxygenates appear to have increased at wells <br /> MW-4 through MW-8 in comparison to the concentrations observed during the previous quarter <br /> analytical data. The historical TPHG, benzene, and MTBE concentration variation over time for these <br /> monitoring wells are presented in Figures 5 through 9. This increasing trend or re-bounce in petroleum <br /> hydrocarbon concentrations in comparison to the first quarter 2002 can be attributed to low operational <br /> uptime of C-SpargeTM system and an increase in groundwater elevations. <br /> During the second quarter 2003, TPHG, benzene, and MTBE were detected in groundwater samples <br /> collected from wells MW-4, MW-8, and MW-10. The highest TPHG, benzene and MTBE concentrations <br /> • were observed in groundwater samples collected from MW-8 at 29,000 µg/L, 6,000 µg/L, and 33,000 <br /> µg/L. MTBE, was also detected in groundwater samples collected from wells MW-1, MW-3 through <br /> I <br /> P:IBp-Arco for URS154691Quarterly12003L9rco 5469_2QR3.doe Or;ZArU5 <br />