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3,2 Dissolved Oxygen <br /> A portable dissolved oxygen sensor was used to measure the concentration in percent DO <br /> and in milligrams per liter(mg/1) at 2-gallon intervals during purging The dissolved oxygen <br /> data are shown in Appendix A, and final readings at the conclusion of purging are tabulated <br /> in Tables 2 and 3 and plotted against time in Figure 3 In contrast to previous months, <br /> concentrations were less than 1% in all wells <br /> 3.3 Hydrocarbons <br /> Eight to ten gallons of water were purged from each monitoring well before sample,, were <br /> collected During purging, the pH, temperature, conductivity, and dissolved oxygen <br /> concentrations of the extracted water were measured with a Corning meter to insw e that <br /> water samples would be representative of unaltered groundwater (Appendix A) To prevent <br /> cross-contamination from MW-2 to the more distant wells, MW-2 was purged and sampled <br /> last The water purged from the wells was stored on site in a 55-gallon drum The sparging <br /> wells were purged of only 1 gallon before they went dry Gasoline odors were noted in <br /> MW-2 and in the vapor extraction and sparging wells <br /> Samples were collected from all ten wells in sterilized vials, labeled, placed in a cooled ice <br /> chest, and transported to Sequoia Analytical Laboratories for hydrocarbon analysis <br /> Laboratory data are summarized in Table 4 The full laboratory report is included in <br /> Appendix B <br /> None of the five gasoline oxygenates were detected in any of the wells, confirming the <br /> results obtained during the first and second quarter monitoring events The results for <br /> gasoline and BTEX are less consistent Benzene has shown a consistent decline in MW-1 <br /> and MW-5, along the margins of the plume, and the benzene plume has shown no <br /> indication of enlarging or migrating In fact, using the September data, the plume app(-ars to <br /> be smaller than it was in the quarter (Figure 4) However, none of the marginal wells is <br /> sufficiently close to an ORC infection boring to have been significantly affected by ORC, <br /> nor have they shown a consistent increase in dissolved oxygen concentrations (Figure 3), so <br /> the decrease in benzene noted in MW-1 and MW-5 is probably not attributable to <br /> oxygenation of the aquifer <br /> Relative to the second quarter, gasoline concentrations decreased in two wells (MW 5 and <br /> SW-1) and increased in four wells (MW-1, MW-2, MW-4, and SW-2) In the certer of <br /> the plume, concentrations increased significantly during the second quarter in SW 1 and <br /> remained much higher in the third quarter, while concentrations in MW-2 are presently <br /> intermediate between their first and second quarter values (Table 4 and Figure 5) At the <br /> margins of the plume, there has been a consistent improvement in MW-5 but not in MW-1 <br /> or MW-4 It is therefore evident that the infection of ORC has not resulted in dramatic <br /> improvement in groundwater quality, and it is unlikely that concentrations will decline to <br /> desired levels by the end of 1998 <br /> 3 <br />