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CLEARWATER GROUP,INC. Groundwater Monitoring and Sampling Protocols Prior to begmning,a decontamination area is established Decontamination procedures consist of scrubbing downhole equipment in an Alconox®solution wash(wash solution is pumped through any purging pumps used),and rinsing in a fust rmse of potable water and a second rmse of potable water or delonized water if the latter is regtured Any non- dedicated down hole equipment is decontaminated prior to use Prior to purging and sampling a well, the static water level is measured to the nearest 0 01 feet with an electronic water sounder Depth to bottom is typically measured once per year,at the request of the project manager,and during Clearwater s first visit to a site If historical analytical data are not available, with w1uch to establish a reliable order of increasing well contamination, the water sounder and tape will be decontaminated between each well If floating separate-phase hydrocarbons (SPH) are suspected or observed, SPH is collected using a clear,open-ended product bailer,and the thickness is measured to the nearest 0 01 feet in the bailer SPH may alternatively be measured with an electronic interface probe Any morutonn&well contammg a measurable tluckness of SPH before or during purging is not additionally purged and no sample is collected from that well Wells containing a hydrocarbon sheen are sampled unless otherwise specified by thepprotfect manager Field observations such as well mtegnty as well as water level measurements and floating product thiclmesses are noted on the Gauging Data/Purge Calculations form Well Ej= Each monitoring well to be sampled is purged using either a PVC bailer or a submersible pump Physical parameters (pH,temperature and conductivity)of the purge water are monitored during purging activities to assess if the water sample collected is representative of the aquifer If required,parameters such as dissolved oxygen,turbidity,salinity etc.are also measured Samples are considered representative if parameter stability is achieved Stability is defined as a change of less than 0 25 pH units, less than 10%change in conductivity in rrucro mhos, and less than 10 degree centigrade(18 degrees Fahrenheit)change in temperature Parameters are measured in a discreet sample decanted from the bailer separately from the rest of the purge water Parameters are measured at least four times dunng purging, initially,and at volume intervals of one well volume Purging continues until three well casing volumes have been removed or until the well completely dewaters Wells which dewater or demonstrate a slow recharge,may be sampled after fewer than three well volumes have been removed Well purging information is recorded on the Purge Data sheet All meters used to measure parameters are calibrated daily Purge water is sealed, labeled, and stored on site in D O T-approved 55-gallon drums After being chemically profiled,the water is removed to an appropriate disposal facility by a licensed waste hauler Groundwater Sample Collection Groundwater samples are collected immediately after purging or,if urgm$rate exceeds well recharge rate,when the well has recharged to at least 80% of its static water,level If recharge is extremely slow, the well is allowed to recharge for at least two hours, if practicable,or until sufficient volume has accumulated for sampling The well is sampled within 24 hours of purging or repurged Samples are collected using polyethylene bailers,either disposable or dedicated to the well Samples being analyzed for compounds most sensitive to volatilization are collected first Water samples are placed in n appro ate laboratory-supplied containers,labeled,documented on a chain of custody form and placed on ice in a cooler for transport to a state-certified analytical laboratory Analytical detection hmits match or surpass standards required by relevant local or regional guidelines 01aal,ty Assurance Procedures To prevent contamination of the samples,CGI personnel adhere to the followmg procedures in the field • A new,clean pair of latex gloves are put on prior to sampling each well • Wells are gauged,purged and groundwater samples are collected in the expected order of increasing degree of contamination based on histoncal analytical results • All purging equipment will be thoroughly decontaminated between each well,using the procedures previously described at the beginning of this section • During sample collection for volatile organic analysis,the amount of air passinthrough the sample is minimized This helps prevent the air from stripping the volatiles from the water Sample bottles are filled by slowly running the sample down the side of the bottle until there is a convex meniscus over the mouth of the bottle The hd is _ carefully screwed onto the bottle such that no air bubbles are present within the bottle If a bubble is present,the cap is removed and additional water is added to the sample container After resealing the sample container,if bubbles still are present inside, the sample container is discarded and the procedure is repeated with a new, container I I[ E 1 I I I E CLEARWATFR GROUP,NC 1 E v 96-1 r' 4 it EI E Ili