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WASTE DISCHARGE RVJIREMENTS ORDER NO. 10 -4- <br /> SAN JOAQUIN COUNTY <br /> FOR POST-CLOSURE AND CORRECTIVE ACTION MONITORING <br /> CORRAL HOLLOW SANITARY LANDFILL <br /> SAN JOAQUIN COUNTY <br /> 22. The Board may specify a non-statistical data analysis method pursuant to Section <br /> 20080(a)(1) of Title 27. Section 13360(a)(1) of the California Water Code allows the <br /> Board to specify requirements to protect underground or surface waters from leakage from <br /> a solid waste site,which includes a method to provide the best assurance of determining the <br /> earliest possible detection of a release. <br /> 23. In order to provide the best assurance of the earliest possible detection of a release of non- <br /> naturally occurring waste constituents from a Unit,this Order specifies a non-statistical <br /> method for the evaluation of monitoring data. <br /> 24. The specified non-statistical method for evaluation of monitoring data provides two criteria <br /> (or triggers) for making the determination that there has been a release of non-naturally <br /> occurring waste constituents from a Unit. The presence of two non-naturally occurring <br /> waste constituents above their respective method detection limit(MDL),or one non- <br /> naturally occurring waste constituent detected above its practical quantitation limit(PQL), <br /> indicates that a release of waste from a Unit has occurred. Following an indication of a <br /> release, verification testing will be conducted to determine whether there has been a release <br /> from the Unit, or there is a source of the detected constituents other than the landfill, or the <br /> detection was a false detection. Although the detection of one non-naturally occurring <br /> waste constituent above its MDL is sufficient to provide for the earliest possible detection <br /> of a release, the detection of two non-naturally occurring waste constituents above the MDL <br /> as a trigger is appropriate due to the higher risk of false-positive analytical results and the <br /> corresponding increase in sampling and analytical expenses from the use of one non- <br /> naturally occurring waste constituent above its MDL as a trigger. <br /> GROUNDWATER DEGRADATION <br /> 25. Volatile organic compounds (VOCs)have been detected in monitoring well MW-5 since <br /> 1991. Recent groundwater analytical results indicate that tetrachloroethylene (PCE) and <br /> vinyl chloride have increasing trends. The fourth quarter 2000 monitoring results show the <br /> concentration of PCE was 5.56 µg/1, while the concentration of vinyl chloride was 0.576 <br /> pg/l. Other VOCs detected in the fourth quarter of 2000 include trichlorofluoromethane, <br /> dichlorodifluoromethane, acetone, benzene, chloroform, 1,1-dichloroethane, cis-1,2- <br /> dichloroethylene, 1,2-dichloropropane,methylene chloride,trichloroethylene, methyl tert- <br /> butyl ether(MTBE), and o-xylene. Other constituents noted to have an increasing trend at <br /> monitoring well MW-5 are electrical conductivity,total dissolved solids, and chloride. <br /> 26. An evaluation of concentrations of VOC compounds in landfill gas at the Corral Hollow <br /> Sanitary Landfill indicates that the impact to groundwater may be the result of diffusion of <br /> VOCs from the gaseous phase to shallow groundwater(The IT Group, July 2000). <br />