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VIGILANT° 4SC <br /> Safety Data Sheet <br /> according to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations <br /> 'SECTION 3: Composition/information on ingredients <br /> 3.1. Substance <br /> Not applicable <br /> 3.2. Mixture <br /> Name Product identifier % GHS-US classification <br /> Bifenazate (CAS No)149877-41-8 40-50 Skin Sens.1,H317 <br /> STOT RE 2,H373 <br /> Aquatic Acute 1,H400 <br /> Aquatic Chronic 1,H410 <br /> 'Chemical name,CAS number and/or exact concentration have been withheld as a trade secret <br /> Full text of hazard classes and H-statements:see section 16 <br /> ,SECTION <br /> 4.1. Description of first aid measures <br /> First-aid measures general Never give anything by mouth to an unconscious person.If medical advice is needed,have <br /> product container or label at hand. <br /> First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing.Artificial respiration and/or <br /> oxygen if necessary. <br /> First-aid measures after skin contact Wash with plenty of soap and water. If skin irritation or rash occurs:Get medical <br /> advice/attention.Take off contaminated clothing and wash it before reuse. <br /> First-aid measures after eye contact Irrigate copiously with clean,fresh water for at least 15 minutes,holding the eyelids apart. <br /> Obtain medical attention if pain,blinking or redness persists. <br /> First-aid measures after ingestion Do NOT induce vomiting.Rinse mouth.Get medical advice/attention. <br /> 4.2. Most important symptoms and effects,both acute and delayed <br /> Symptoms/injuries May cause damage to organs through prolonged or repeated exposure. <br /> Symptoms/injuries after skin contact May cause an allergic skin reaction. <br /> 4.3. Indication of any immediate medical attention and special treatment needed <br /> Treat symptomatically. <br /> • Firefighting <br /> 5.1. Extinguishing media <br /> Suitable extinguishing media Carbon dioxide. Dry powder.Water fog.alcohol resistant foam. <br /> Unsuitable extinguishing media Water spray. <br /> 5.2. Special hazards arising from the substance or mixture <br /> Fire hazard Burning produces irritating,toxic and noxious fumes. <br /> Reactivity No dangerous reactions known. <br /> 5.3. Advice for firefighters <br /> Firefighting instructions Use extinguishing media appropriate for surrounding fire.Do not allow run-off from fire fighting <br /> to enter drains or water courses. <br /> Protection during firefighting Wear a self contained breathing apparatus.Wear fire/flame resistant/retardant clothing. <br /> SECTIONAccidental <br /> 6.1. Personal precautions,protective equipment and emergency procedures <br /> General measures Avoid contact with skin,eyes and clothing.Use personal protective equipment as required.Do <br /> not breathe aerosol. <br /> 6.1.1. For non-emergency personnel <br /> Protective equipment Refer to section 8.2. <br /> Emergency procedures Evacuate unnecessary personnel. <br /> 6.1.2. For emergency responders <br /> Protective equipment Refer to section 8.2. <br /> Emergency procedures Ventilate area.Stop leak if safe to do so. <br /> 6.2. Environmental precautions <br /> Do not discharge into drains or the environment.Prevent entry to sewers and public waters. <br /> 09/26/2016 EN(English) SDS ID:AMD1606002 2/8 <br />