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Stantec <br /> April 30, 2010 <br /> Page 6 of 14 <br /> Reference: First Quarter 2010 Site Status, Groundwater Monitoring and Remedial Summary Report-Stockton <br /> Terminals Technical Committee Facilities <br /> • Remedial Observation Well PS/MW-18 - TPHg and BTEX concentrations were at <br /> non-detectable levels, while concentrations of MTBE (7.7 pg/L) and TBA (22 pg/L) both <br /> decreased from fourth quarter 2009 (52 and 300 pg/L, respectively). MTBE and TPHd <br /> concentrations decreased by 91 percent since August 2004 (prior to startup of East <br /> System); TBA decreased by 96 percent. <br /> • Treatment Area Well TS/MW-1A - Toluene, ethylbenzene, xylenes, and TBA were <br /> non-detect during first quarter. Since August 2004 (prior to the startup of the West System), <br /> hydrocarbon concentrations have decreased by over 97 percent for TPHg and over <br /> 99 percent for benzene and MTBE. <br /> • The Site's first quarter maximum MTBE concentration (9,700 pg/L) decreased 97 percent <br /> from the historical maximum (290,000 pg/L in 1999), while the first quarter maximum <br /> benzene concentration (8,000 pg/L) decreased 82 percent from the historical maximum <br /> (45,000 pg/L in 1993) (Appendix Table D-1). <br /> • Over 56 percent of the wells are below the WQOs and/or MRLs for the respective analytes, <br /> except TPHg and benzene. <br /> 3.5.2 "B" Zone Groundwater Quality Data <br /> Groundwater samples were collected from 18 "B" zone wells (Table 1 and Appendix Table D-2). <br /> Well AR/MW-14B was inaccessible due to terminal operations and could not be sampled. The <br /> overall trend in the "B" zone has been decreasing concentrations across the site. Consistent with <br /> this trend, dissolved TPHg, TPHd, BTEX, and MTBE groundwater concentrations in the "B" zone <br /> were decreasing or within historical ranges during first quarter 2010, with the following few <br /> exceptions: <br /> • Well AR/MW-5B - Benzene (81 pg/L) increased from fourth quarter 2009 (69 pg/L). <br /> Benzene concentrations in this well have been gradually increasing. Most other analyte <br /> concentrations from this well have decreased significantly since fourth quarter 2008. <br /> • Well AR/MW-9B - Benzene (720 pg/L), toluene (5.2 pg/L), TPHg (1,900 pg/L), and MTBE <br /> (15 pg/L) concentrations exceeded fourth quarter 2009 concentrations of 590 pg/L, 3.2 pg/L, <br /> 1,600 pg/L, and 9.1 pg/L, respectively. <br /> • Well TO/WC-2B - MTBE (300 pg/L) exceeded the fourth quarter 2009 concentration of <br /> 250 pg/L. MTBE concentrations in this well have been gradually increasing. All other <br /> analytes are within historical ranges. <br /> Several noteworthy decreases are mentioned below. <br /> • Treatment Zone Well TS/MW-1B - Since August 2004 (prior to the startup of the West <br /> System), hydrocarbon concentrations have decreased by over 99 percent for TPHg, <br /> benzene, and MTBE; while TPHd decreased by over 93 percent and TBA decreased by <br /> 91 percent. <br />