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$I antec <br /> Work Plan for Amended Bioremediation Pilot Study <br /> BP Terminal 40T <br /> November 10, 2008 <br /> was injected into each well at a rate of 0.2 gallons per minute (gpm). Approximately 240 gallons <br /> of the solution were pumped into each well over a period of approximately 18 hours. The <br /> injection events began on May 25, 2004 and were performed weekly until June 22, 2004. <br /> Injections were temporarily stopped after the fifth event because the levels of sulfide exceeded <br /> the baseline limits set for monitoring well AR/MW-1A. The injections were restarted in August <br /> 2004, following a change in the baseline levels. During the course of the URS pilot study, a <br /> total of 11 nitrate/sulfate injection events were performed, during which, approximately 7,920 <br /> gallons of the nitrate/sulfate solution were injected. <br /> URS concluded that the impact of the nitrate/sulfate injections on the hydrocarbon <br /> concentrations only appeared to be significant near the injection points. GRO and benzene <br /> concentrations in groundwater monitoring well AR/MW-5A decreased compared to groundwater <br /> monitoring wells farther from the point of injection. Therefore, the pilot study indicated that <br /> nitrate/sulfate injections may be able to remediate dissolved hydrocarbons at the site (Pilot <br /> Study Evaluation Report Enhanced Bioremedation Pilot Study, URS, 2005). <br /> Stantec submitted a work plan to the RWQCB on May 7, 2007 for injection of nitrate/sulfate as <br /> part of the Enhanced Bioremediation Pilot Study (SECOR, 2007). The RWQCB developed a <br /> waste discharge requirement permit using background concentrations the previously <br /> established for groundwater based on the URS-2005 study. The problem with the background <br /> concentrations were that many of on-site wells contained groundwater with concentrations <br /> above background level for the salts proposed for treatment. Due to potential problems <br /> associated with determining background level of nitrate, phosphate, and other salts being used <br /> as part of the proposed nitrate/sulfate treatment system. Stantec determined that the best <br /> approach would be to limit addition to calcium sulfate. Use of calcium sulfate reduced the <br /> potential that groundwater concentrations in down gradient point of contingency wells would <br /> exceed background levels and require some sort of mitigation. <br /> GEOLOGY AND HYDROGEOLOGY <br /> Unconsolidated strata beneath the Stockton area consist primarily of interbedded clays, silts, <br /> and fine grained sands of the Quaternary age flood basin deposits. The flood basin deposits <br /> attain a thickness of approximately 1,000 ft in the Stockton area and were deposited by fluvio- <br /> deltaic processes. Based on previous work, the lithology has been generally subdivided into five <br /> zones based on the distribution of fine- and coarse-grained sedimentary units defined as the A- <br /> zone, the B-zone, the B/C-aquitard, the C-zone, and D-zone. <br /> A-zone <br /> The A-zone extends from ground surface to a depth of approximately 20 to 25 ft bgs. The A- <br /> zone hydraulic gradients vary from 0.001 to 0.005 foot per foot (ft/ft), and the flow is generally <br /> toward the southeast. Downward vertical gradients of 0.001 to 0.24 ft/ft were typically observed <br /> in the A-zone and B-zone paired monitoring wells during quarterly events. <br /> B-zone <br /> The B-zone underlies the A-zone and extends to an approximate depth of 40 to 45 ft bgs. <br /> Differentiation of the A-zone and B-zone is based on differing aquifer properties of the <br /> unconfined A-zone and the confined B-zone, and variation of the general mineral quality <br /> parameters. The B-zone hydraulic gradients vary from 0.002 to 0.004 ft/ft and flow toward the <br /> 40T Work Plan for Amended Bioremediation Pilot Study.doc 4 <br />