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L & M OPERABLE UNIT-THIRD QUARTER 2014 SITE STATUS, REMEDIAL SUMMARY, <br /> AND GROUNDWATER MONITORING REPORT <br /> Groundwater Monitoring and Sampling <br /> October 31, 2014 <br /> 2.3.2.4 Quality Assurance/Quality Control Samples <br /> Stantec's equipment blanks (QCEB-I-PV, QCEB-2-PV, QCEB-3-PV, and QCEB-4-PV) were <br /> analyzed for the presence of petroleum hydrocarbons compounds. All constituents <br /> were reported as non-detect at or above the laboratory MRL in the equipment blanks, <br /> indicating that no cross-contamination occurred during the sampling activities. <br /> Duplicate samples QCDUP-1 and QCDUP-3 were collected from L&M OU A-Zone wells <br /> MW-18 and MW-21, respectively, during the 3Q14 sampling event. A comparison of the <br /> samples is shown on the following table. <br /> Analyte Sample # Sample # % Difference <br /> MW-18 QCDUP-1 <br /> TPH (mg/L 3.5 3.5 Oho <br /> TPHd (mg/L 1.3 1.3 Oho <br /> TPHo (mg/L 0.063 0.083 +/- 27.47o <br /> Benzene <0.0005 <0.0005 Oho <br /> m /L <br /> MTBE (mg/L <0.0005 <0.0005 Oho <br /> TBA (mg/L <0.005 <0.005 0% <br /> Analyte Sample # Sample # 7o Difference <br /> MW-21 QCDUP-3 <br /> TPHg (mg/L) <0.50 <0.50 Oho <br /> TPHd (mg/L) 0.81 0.80 +/- 1.247o <br /> TPHo (mg/L 0.068 0.06 +/- 12.57o <br /> Benzene <0.0005 <0.0005 Oho <br /> (mg/L) <br /> MTBE (mg/L <0.0005 <0.0005 0% <br /> TBA (mg/L) <0.005 <0.005 Oho <br /> The calculated Relative Percent Difference (RPD) between sample MW-18 and <br /> QCDUP-1 were within the acceptable limit (-20%), except for the concentrations of <br /> TPHo (-27.40), which was slightly outside the preferred quality control range. The <br /> calculated Relative Percent Difference (RPD) between sample MW-21 and QCDUP-3 <br /> were within the acceptable limit (-20%). These concentrations are consistent with <br /> historical data and only slightly outside the recommended acceptable % difference <br /> range; thus, the data can be considered representative. <br /> 2.3.2.5 General Laboratory Notes <br /> The following validation notes are consistent with the shallow zone quality assurance <br /> and quality control. Each set of issues corresponds directly with the denoted report <br /> (Appendix E). <br /> 5ta ntec 2.6 <br />