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I. of 10 mg/l. PMCL's are derived from health based criteria (by California Depaftment of Health <br />Services from public health goals from one in a million [101 incremental cancer risk estimates for <br />carcinogens and threshold toxicity levels for non-carcinogens. The relatively high concentrations <br />of TKN in the soils may be an indicator of a possible source of the nitrate as NO3 and total <br />nitrogen concentrations noted in the groundwater sample. In MW-2 the concentrations of the <br />fertilizer constituents showed a decreasing trend with depth in the boring. The reduction ranged <br />from >55% (phosphate) to >88% (ammonia as N) from 1-foot to 10-foot. The soils encountered in <br />MW-2 were noted as showing some of the highest concentrations of ammonia as N, nitrate as <br />NO3, total nitrogen, nitrate+nitrite (N), TKN, and phosphate compared to the other soil borings <br />advanced for MW-1 or MW-3. MW-2 is located on the northern boundary of the site and <br />downgradient of approximately 1/4 of the site where vehicles were parked in the past and in close <br />proximity of the tank washout pad/sump. <br />The groundwater sample in MW-3 showed no concentrations at or above the applicable WQGs for <br />the fertilizer constituents, but it should be noted that TKN concentrations in MW-3 may be a <br />potential source for nitrates in water. The soil samples collected from MW-3 also showed <br />decreasing concentrations with depth in the 1-foot and 5-foot samples analyzed. (The 10-foot <br />sample was not analyzed and put on hold). As seen in the other sample locations discussed the <br />concentrations decreased by up to >60% (nitrate as NO3). It should be noted that MW-3 is <br />located near the sites northwest boundary and downgradient to the site. Additionally, this portion <br />of the site has been paved and had not been noted from Kleinfelder's Phase I report as having <br />typical operations such as storage or mixing of chemicals in this portion of the site. <br />Concentrations of the fertilizer constituents found in MW-3 may be indicative of naturally <br />occurring conditions. <br />The water sample collected from the domestic well on site showed no detectable concentrations of <br />ammonia as N, TKN, and phosphate. The detected concentrations of nitrate as NO3 and total <br />nitrogen poses a risk due to the elevated concentrations seen in the sample. The nitrate as NO3 <br />concentration (209 mg/1) and total nitrogen (47 mg/1) exceeds the MCLs of 45 mg/1 and 10 mg/1 <br />respectively. There may be an offsite source of these constituents or an existing background <br />condition as the domestic well is from a deeper portion of the aquifer. There was also detections <br />of 1,2-Dichloropropane and 1,2,3-Trichloropropane in the domestic water supply well. The 1,2- <br />Dichloropropane concentration was 0.049 mg/1, above the PMCL of 0.005 mg/l. The <br />concentration of 1,2,3-Trichloropropane was 0.004 mg/1, below the MCL of 0.042 mg/l. As <br />referenced from the "Handbook of Environmental Data on Organic Chemicals", Edition, by <br />Verschueren; 1,2-Dichloropropane has been used in fumigants and as an anti-knock lead <br />scavenger. The biological effects for humans is mild skin irritation. The extent or source for these <br />compounds are unknown at this time, and may be present due to an off site source as neither <br />compound was detected in the shallow soil samples collected at the site or from the shallow <br />groundwater samples. <br />The four groundwater samples collected at the site showed no detectable concentrations of DBCP <br />at or above the laboratory reporting limits. There was however, one detection of EDB in MW-2 <br />with a concentration of 0.04 ugh, below the MCL. The MCL for EDB is 0.05 ug/l. It should be <br />noted again that no concentrations of EDB were detected at or above the laboratory reporting limit <br />27125.E01 / STO4R181 <br /> <br />Page 20 of 23 <br />0 2004 Kleinfelder, Inc. February 13, 2004 <br />KLEINFELDER 2825 East Myrtle Street, Stockton, CA 95205-4794 (209) 948-1345 (209) 948-0621 fax