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INFORMATION SHEET ORDER NO. R5-2015-0012 <br />6 <br />IN-SITU REMEDIATION OF GROUNDWATER AND <br />DISCHARGE OF TREATED GROUNDWATER TO LAND <br />Amendment Delivery <br />The in-situ treatment system is usually one of three types. One type utilizes a <br />groundwater recirculation consisting of extraction and injection wells and <br />provides control of the injectants and treatment zone. The extracted <br />groundwater is amended aboveground and the amended water recharged <br />upgradient of the extraction well. The second type injects the amendments into <br />the groundwater and allows the groundwater to flow though the treatment zone. <br />The third type uses extraction and injection wells to create a barrier with the <br />treatment zone being established within and downgradient of the capture zone of <br />the injection well(s). In this type of system the injection tends to occur <br />downgradient of the extraction wells. The use of extraction and recharge <br />systems is preferred as it provides greater flexibility and controi of the treatment <br />zone, and can be operated to help restore the treatment zone to pre-project <br />conditions after remediation of the initial pollution has been completed. <br />Amendments <br />These waste discharge requirements require that the injectant materials be <br />analyzed to determine the suitability of the materials to be used for in-situ <br />remediation. Past analyses of various amendments, including corn syrup, <br />molasses, HRCTIvi and edible oils have shown elevated concentrations of sodium <br />and other salts, and trace metals in some of them. As the groundwater in the <br />Central Valley is in many places adversely impacted by salts, the use of salt- <br />containing amendments is discouraged. A project that proposes using a salt- <br />containing amendment is required to demonstrate that there is no cost-effective, <br />salt-free amendment that can be utilized to achieve adequate remediation of the <br />pollution before allowing the salt-containing amendment to be used. In addition, <br />amendments containing other pollutants such as metals could contribute to <br />exceedances of water quality objectives and/or degradation of the groundwater. <br />Basin Plan, Beneficial Uses, Background Groundwater Quality and Water <br />Quality Objectives <br />The Water Quality Control Plan for the California Regional Water Quality Control <br />Board Central Valley Region, Fourth Edition (Basin Plan), designates beneficial <br />uses, establishes water quality objectives, and contains implementation plans <br />and policies for all waters of the Basin. Beneficial uses often determine the water <br />quality objectives that apply to a water body. For example, waters designated as <br />municipal and domestic supply must meet the maximum contaminant levels <br />(MCLs) for drinking waters. The Basin Plan sets forth the applicable beneficial <br />uses (industrial, agricultural, and domestic supply in this instance) of <br />groundwater, procedure for application of water quality objectives, and the <br />process for and factors to consider in allocating waste assimilation capacity.