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MONITORING AND REPORTING PROGRAM ORDER NO R5-2015-0012-0021 <br />5 <br />BOULEVARD AUTOMOTIVE SERVICE <br />SAN JOAQUIN COUNTY <br />5 Should adverse water quality conditions occur due to the injection of oxidants, injections shall cease and those wells showing impacts will <br />be monitored and bulk purged for the injection permit constituents of concern in Suite B as identified during the full-scale, until baseline is <br />reached, per Finding 3, page 2, paragraph 2 above <br />Table 2: Analytical Methods <br />Constituent Method' Maximum Practical <br />Quantitation Limit (pg/L)2 Frequency <br />Suite A <br />TPH-g GC/MS 50 <br />As indicated in <br />Table 1 <br />BTEX, MTBE, TAME, <br />DIPE, ETBE, TBA, 1,2- <br />DCA, EDB <br />EPA 8260B 0.5 -10 <br />Suite B <br />As indicated in <br />Table 1 <br />Metals, dissolved3 EPA 200.7/200.8 0.025 - 500 <br />Hexavalent Chromium EPA 218.6 0.2 <br />Anions4 EPA 300.1 5-1000 <br />Ammonia as N EPA E350.1 100 <br />TDS EPA SM2500 10 <br />1 Or an equivalent EPA Method that achieves the maximum Practical Quantitation Limit. <br />2 All concentrations between the Method Detection Limit and the Practical Quantitation Limit shall be reported as an estimated value (J flag). <br />3 Dissolved metal analyses include Al, As, Ba, Be, Ca, Cd, Cr, Co, Cu, Fe, Hg, Mg, Mn, Mo, Ni, Na, Pb, Sb, TI, V, W, and Zn and are <br />collected in laboratory-supplied non-preserved container, relinquished to the lab for filtering and preservation prior to analyses. <br />4 Anions include bromide, bromate, chloride, nitrate, nitrate as N, nitrite as N, and sulfate <br />FIELD SAMPLING <br />3. In addition to the above sampling and analysis, groundwater elevation, electrical <br />conductivity, DO, ORP, pH, and water temperature will be measured in the field each time a <br />monitoring well is sampled. The sampling and analysis of field parameters is specified in <br />Table 3. <br />Table 3: Field Sampling Requirements <br />Parameters Units Type of Sample <br />Groundwater Elevation Feet, North American Vertical <br />Datum 88 <br />Measurement& <br />Calculation <br />Water Temperature Degrees Celsius Grab <br />Electrical Conductivity uhmos/cm Grab <br />Dissolved Oxygen mg/L Grab <br />pH pH Units (to 0.1 units) Grab <br />Field test instruments (such as those used to test pH and dissolved oxygen) may be used <br />provided that: <br />The operator is trained in proper use and maintenance of the instruments; <br />The instruments are calibrated prior to each monitoring event;