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12066.002.000 <br />San Joaquin County Environmental Health Department <br />November 30, 2018 <br />Mountain House Neighborhood A, Units 3 and 4 <br />Revised January 22, 2019 <br />SOIL GAS CHARACTERIZATION REPORT <br />Page 3 <br />For the purposes of this characterization, the three soil gas samples were analyzed for the <br />following: <br />Volatile Organic Compounds (VOCs), including TPH-g, by EPA Test method TO-15. <br />January 10, 2019 Sampling Event <br />Based on review of the November 2018 ENGEO soil gas data, San Joaquin County <br />Environmental Health Department (SJCEHD) expressed concerns regarding a leak check <br />compound, 1,1-difluoroethane (DFA), detected at sample location SG-5. The reported DFA <br />concentrations were greater than 10 times the detection limit for Benzene. Based on DTSC <br />guidelines, this could suggest a potential bias in the soil gas data for SG-5. The SJCEHD has <br />requested retesting of the SG-5 location to confirm soil gas results. In addition, it was agreed that <br />two additional locations would be sampled northeast of the pipeline ROW, proximate to the graded <br />residential lots, to determine if potential lateral migration of soil gas has occurred (Figure 2). <br />To further delineate the extent of VOCs in soil gas on the Property, sampling was performed at <br />three locations (SG-5, SG-11, and SG-12 @ 10') (Figure 2). Consistent with the November 2018 <br />event, the soil gas samples were recovered in accordance with Department of Toxic Substances <br />Control (DTSC) Final Advisory Active Soil Gas Investigations (July 2015). 2-propanol (IPA) was <br />used as a leak check compound. The soil gas samples will be recovered from each of the three <br />locations at a depth of 10 feet below the existing ground surface. <br />For the purposes of this characterization, the three soil gas samples were analyzed for the <br />following: <br />Volatile Organic Compounds (VOCs), including TPH-g, by EPA Test method TO-15. <br />In addition to the soil gas sampling, grab groundwater sampling was attempted within a separate <br />boring adjacent to SG-5; however, refusal was encountered at a depth of 37 feet, with no <br />groundwater encountered. <br />ANALYTICAL RESULTS <br />Soil Gas Samples <br />November 20, 2018 Sampling Event <br />Seven discrete samples reported detectable concentrations of TPH-gasoline, ranging from <br />210 micrograms per cubic meter (ug/m3) to 1650 ug/m3 in samples SG-5 at 5 feet and SG- 6 at <br />10 feet, respectively. These concentrations are below applicable RWQCB Tier 1 Environmental <br />Screening Levels (ESLs). TPH-Gasoline was reported as non-detectable in the three discrete <br />samples SG-8 at 5 feet, and in both SG-9 samples at 5 and 10 feet. <br />Multiple samples reported low-level concentrations of several VOCs; the following are the <br />maximum concentrations observed for these analytes: Acetone (400 ug/m3), Carbon Disulfide <br />(12 ug/m3), Benzene (33 ug/m3 ), Toluene (36 ug/m3 ), 4-Methyl-2-Pentanone (MIBK) (17 ug/m3), <br />Xylenes (14.6 ug/m3), Styrene (4.9 ug/m3), Hexane (40 ug/m3), 2-Hexanone (9.9 ug/m3), <br />2-Butanone(MEK) ( 110 ug/m3 ),Tetrahydrofuran (240 ug/m3), Napthalene (3.0 ug/m3), and <br />tert-Butanol (13 ug/m3 ). All of these concentrations reported are below applicable RWQCB Tier 1 <br />ESLs, DTSC Modified Screening Levels, and USEPA RSLs.