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Simplot UAN-32 Urea Ammonium Nitrate Solution 32-0-0 Safety Data Sheet according to Federal Register/Vol.77,No.58 I Monday,March 26,2012/Rules and Regulations First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing.Allow affected person to breathe fresh air.Allow the victim to rest. First-aid measures after skin contact Remove affected clothing and wash all exposed skin area with mild soap and water,followed by warm water rinse.Wash skin with plenty of water. First-aid measures after eye contact IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing.Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing. If eye irritation persists:Get medical attention. First-aid measures after ingestion Rinse mouth.Do NOT induce vomiting.Obtain emergency medical attention.Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects(acute and delayed) Potential adverse human health effects and Based on available data,the classification criteria are not met. symptoms Symptoms/effects after eye contact Causes eye irritation.mild eye irritation. 4.3. Immediate medical attention and special treatment,if necessary Treat symptomatically. SECTION 5.1. Suitable(and unsuitable)extinguishing media Suitable extinguishing media Sand.Water spray.Dry powder.Foam.Carbon dioxide. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Hazardous decomposition products in case of Toxic fumes may be released. fire 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire.Prevent fire fighting water from entering the environment. Protection during firefighting Do not enter fire area without proper protective equipment,including respiratory protection.Do not attempt to take action without suitable protective equipment.Self-contained breathing apparatus.Complete protective clothing. SECTION 6.1. Personal precautions,protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures Ventilate spillage area.Evacuate unnecessary personnel.Avoid contact with skin and eyes. 6.1.2. For emergency responders Protective equipment Do not attempt to take action without suitable protective equipment.Equip cleanup crew with proper protection. For further information refer to section 8:"Exposure controls/personal protection". Emergency procedures Ventilate area. 6.2. Environmental precautions Avoid release to the environment.Prevent entry to sewers and public waters.Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Take up liquid spill into absorbent material.Soak up spills with inert solids,such as clay or diatomaceous earth as soon as possible.Collect spillage.Store away from other materials. Other information Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8.Exposure controls and personal protection.For further information refer to section 13. SECTION • • and storage 7.1. Precautions for safe handling Precautions for safe handling Ensure good ventilation of the work station.Wash hands and other exposed areas with mild soap and water before eating,drinking or smoking and when leaving work.Provide good ventilation in process area to prevent formation of vapour.Avoid contact with skin and eyes. Wear personal protective equipment. 02/09/2021 EN(English) 2/7