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Methods and materials for containment and cleaning up <br /> Avoid dispersal of dust in the air (e . g. clearing dust surfaces with compressed air) . Clean-up spills <br /> immediately using non-sparking utensils . Wet down spilled materials prior to initiating clean-up and keep <br /> material wet until ready for disposal . Avoid contamination of water bodies during clean up and disposal . <br /> This material is heavier than water. Create an overflow dam with filtration capabilities to retain material . <br /> Collect dust using a vacuum cleaner equipped with HEPA filter. Large Spills : Sweep, shovel or vacuum <br /> up spillage and collect in suitable container for disposal . For a spillage into water: where possible, remove <br /> any intact containers from the water. Clean contaminated surfaces thoroughly to remove residual <br /> contamination . Never return spilled material to original containers for re -use . For waste disposal , see <br /> section 13 of this SDS . <br /> Section 7 - HANDLING AND STORAGE <br /> Precautions for Safe HandlinE <br /> Do not handle until all safety precautions have been read and understood . Do not subject to mechanical <br /> shock . Avoid exposure to sunlight or artificial ultraviolet light. Minimize dust generation and accumulation . <br /> Provide appropriate exhaust ventilation . Avoid breathing dust . Avoid contact with eyes , skin and clothing . <br /> Do not taste or swallow. Wear appropriate personal protective equipment. Observe good industrial hygiene practices . <br /> Smokeless powder contains stabilizers and deteriorates very slowly under proper storage conditions . Old smokeless powder <br /> should be checked for deterioration regularly . Deteriorating smokeless powder produces an acidic odor and may produce <br /> reddish -brown fumes . Dispose of deteriorating smokeless powder through , for example, controlled open burning in small <br /> quantities (products should be submerged in water until burned) . Smokeless powder should not be exposed to excessive <br /> heat, as this can accelerate deterioration . Deterioration produces an acidity that accelerates further reaction and has been <br /> known, because of heat generated by the reaction, to cause spontaneous combustion . <br /> Conditions for safe storage, including any incompatibilities <br /> Store at 21 ° C (70°F) , 50% relative humidity (decomposition becomes measurable above 50°C ( 122 °F) . <br /> Store in original container. Keep container tightly closed . Store in a cool , dry, well -ventilated place away <br /> from all sources of ignition . Store away from incompatible materials (see Section 10 of this SDS) . <br /> For additional information regarding handling and storage guidelines , see "Properties and Storage of <br /> Smokeless Powder" published by the SPORTING ARMS AND AMMUNITION MANUFACTURERS <br /> INSTITUTE, INC ( SAAMI) , 11 Mile High Road, Newtown , CT 06405 (www . saami . org) <br /> Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION <br /> Control Parameters <br /> Occupation Exposure Limits OEL <br /> Chemical Name CAS Number ACGIH TLV OSHA PEL Other Information <br /> Nitrocellulose 9004-70-0 None established None established <br /> Nitroglycerin 55-63 -0 0.05 ppm Skin 0.2 ppm 2.0 mg/m3 Air sampling alone is insufficient <br /> Designation OSHA limit applies to skin to accurately quantify exposure. <br /> Measures to prevent significant <br /> Cutaneous absorption may be <br /> re aired. <br /> Dibut I Phthalate 84-74-2 5 mg/m3 5 nt nO <br /> Polyester Adipate Not Available Not Available Not Available <br /> Ethyl Centralite 85-98-3 None established None established <br /> dieth tdi 9ren lures) <br /> Rusin 8050-09-7 None established None established <br /> Arkadile 11 13114-72-2 None established None established <br /> Potassium Nitrate 7757-79- 1 None established None established <br /> Potassium Sulfate 7778-80-5 None established None established <br /> Ethyl Acetate 141 -78-6 400 ppm 400 ppm 1400 mg/m3 <br /> Diphenylamine 122-39-4 10 nig/m3 None <br /> established <br /> N-Nitrosodiphenylamine 86-30-6 None None established <br /> established <br /> Tin Dioxide 18282- 10-5 2 mg/ni3 2 nig/nA Tin oxide and inorganic <br /> compounds <br /> Calcium Carbonate 1317-65-3 None established 15 mg/m3 (total dust) 5 nig/m3 <br /> (respirable fraction <br /> Graphite 7782-42-5 2 mg/m3 (respirable 15 mg/m3 (total dust) 5 nig/m3 <br /> fraction) I ((respirable fraction) <br />