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GROUND WATER IN THE CENTRAL VALLEY, CALIFORNIA A41 <br />that ground-water quality is degrading as a result of <br />increasing application of agricultural chemicals and <br />growth of urban population. <br />The concentrations of dissolved solids increased signif- <br />icantly since the 1950's throughout the Sacramento <br />Valley except for an area south of Sutter Buttes between <br />the Sacramento and Feather Rivers (Hull, 1984). How- <br />ever, increases in nitrate concentrations were found only <br />on the west side and in the southeastern part of the valley <br />(Hull, 1984). Hull (U.S. Geological Survey, oral com- <br />mun., 1984) indicated that the rate of nitrate build-up has <br />been increasing since 1912. He found that in 1912 to 1913, <br />2.2 percent of the wells had nitrate concentrations <br />greater than 5.5 mg/L; between 1960 and 1969, 4.9 <br />percent had concentrations exceeding 5.5 mg/L, and from <br />1974 to 1978, 10.5 percent had concentrations exceeding <br />5.5 mg/L. <br />Studies to determine human impact on ground-water <br />quality in the San Joaquin Valley were not done, largely <br />because different time periods of sample collection and <br />the use of different analytical techniques make the <br />comparability of the existing data questionable. Because <br />agricultural practices in the San Joaquin Valley are <br />similar to those in the Sacramento Valley, it is likely that <br />ground-water quality in the San Joaquin Valley is also <br />degrading as a result of human activities. However, <br />differences in geology, soils, and irrigation techniques <br />could all affect the impact of human activities. Areas of <br />possible contamination of ground water due to human <br />activities in the San Joaquin Valley were mapped by <br />Templin (1984, pi. 8). Sources listed were industrial, <br />municipal and domestic solid-waste disposal sites, and <br />agricultural chemical build-up. This map suggests that <br />human-induced contamination exists throughout much of <br />the valley. <br />The use of pesticides is another possible impact on <br />ground water that has not been studied in detail. <br />Pesticides have been used intensively in the Central <br />Valley for many years and because dissolved-solids and <br />nitrate concentrations are increasing, it is likely that <br />pesticide concentrations in ground water also are increas- <br />ing. <br />The presence of dibromochloropropane (DBCP) in <br />ground water in the San Joaquin Valley was mapped by <br />Templin (1984, pi. 7D). The presence of this pesticide at <br />levels above 0.0005 mg/L near Bakersfield, Fresno, <br />Modesto, and north of Merced and Stockton coincides <br />with land-use patterns. More specifically, these areas are <br />occupied by orchards and vineyards, where DBCP is <br />commonly used. The presence of DBCP in the San <br />Joaquin Valley suggests that other pesticides have prob- <br />ably built up in ground water of the Central Valley. <br />Selenium, which is toxic to humans and animals at very <br />low concentrations, occurs naturally in the soils and <br />ground water on the west side of the San Joaquin Valley <br />(Deverel and others, 1984). Ecological and health effects <br />of selenium and other trace elements in agricultural <br />drainage water on the west side of the San Joaquin Valley <br />have become subjects of extensive study since high <br />incidences of mortality and birth defects were observed <br />in waterfowl nesting in the area where drainage water is <br />discharged (U.S. Bureau of Reclamation, 1984). In a <br />preliminary study (Deverel and others, 1984), the areal <br />distribution of selenium and other inorganic constituents <br />was examined along the west side of the valley west of <br />Fresno. Selenium concentrations (median concentrations <br />of 10-11 mg/L) were highest in the central and southern <br />parts (south of Los Banos and south of Mendota) of the <br />area studied. Extensive studies by U.S. Department of <br />Interior agencies (Bureau of Reclamation, Fish and <br />Wildlife Service, and the Geological Survey) and also <br />many studies by universities, State water resources <br />agencies, and concerned local agencies are still in <br />progress (1989). <br />SELECTED REFERENCES <br />Ayers, R.S., 1977, Quality of water for irrigation: Proceedings of the <br />American Society of Civil Engineers, Journal of the Irrigation and <br />Drainage Division, v. 103, no. IR2, p. 135-154. <br />Back, William, 1961, Techniques for mapping of hydrochemical facies, <br />in Geological Survey research, 1961: U.S. Geological Survey <br />Professional Paper 424-D, p. D380-D382. <br />Bailey, E.H., Blake, M.C., Jr., and Jones, D.L., 1970, On-land <br />Mesozoic crust in California Coast Ranges: U.S. Geological Survey <br />Professional Paper 700-C, p. C70-C81. <br />Bennett, G.D., 1979, Regional ground-water systems analysis: Water <br />Spectrum, fall 1979, p. 36-42. <br />Berkstresser, C.F., Jr. 1973, Map showing base of fresh ground-water, <br />approximately 3,000 micromhos, in the Sacramento Valley and <br />Sacramento-San Joaquin Delta, California: U.S. Geological Survey <br />Water-Resources Investigations Report 40-73, 1 sheet. <br />Berkstresser, C.F., Jr., French, J.J., and Schaal, M.E., 1985, Data for <br />four geologic test holes in the Sacramento Valley, California: U.S. <br />Geological Survey Open-File Report 85-488, 110 p. <br />Bertoldi, G.L., 1971, Chemical quality of ground water in the Dos <br />Palos-Kettleman City area, San Joaquin Valley, California: U.S. <br />Geological Survey open-file report, 45 p. <br /> 1976, Chemical quality of ground water in the Tehama-Colusa <br />Canal service area, Sacramento Valley, California: U.S. Geological <br />Survey Water-Resources Investigations Report 76-92, 44 p. <br /> 1979, A plan to study the aquifer system of the Central Valley <br />of California: U.S. Geological Survey Open-File Report 79-1480, <br />48 p. <br />Blair, T.A., andFite, R.C., 1957, Weather elements: Englewood Cliffs, <br />New Jersey, Prentice-Hall, 414 p. <br />Bloyd, R.M., Jr., 1978, Ground-water conditions in the Sacramento <br />Valley, California, 1912, 1961, and 1971, in Evaluation of ground- <br />water resources Sacramento Valley: California Department of <br />Water Resources Bulletin 118-6, p. 97-136. <br />Brown, Eugene, Skougstad, M.W., and Fishman, M.J., 1970, Methods <br />for collection and analysis of water samples for dissolved minerals <br />and gases: U.S. Geological Survey Techniques of Water-Resour-