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ENVIRONMENTAL AGRICULTURAL <br />Analytical Chemists <br />July 2, 2021 <br />Lab ID : STK2139039 <br />Simplot Growers Solution Customer : 3-14814 <br />Quality Control - Inorganic <br />Constituent Method Date/ID Type Units Conc. QC Data DQO Note <br />Metals <br />Phosphorus 3050 06/29/21:207296JZA Blank mg/kg ND <5 <br />LCS mg/kg 200.0 105 % 80-120 <br />MS mg/kg 194.2 484% <1/4 <br />(V12144514-00I) MSD mg/kg 190.5 334% <1/4 <br />MSRPD mg/kg 38.10 4.8% <30 <br />PDS mg/kg 196.1 643% 75-125 430 <br />Sodium 3050 06/29/21:207296JZA Blank mg/kg ND <50 <br />LCS mg/kg 600.0 110% 85-115 <br />MS mg/kg 582.5 246% 75-125 435 <br />(V12144514-001) MSD mg/kg 571.4 223% 75-125 435 <br />MSRPD mg/kg 38.10 4.9% <20.0 <br />PDS mg/kg 588.2 229% 75-125 430 <br />Phosphorus 6010B 06/30/21:209986AC CCV ppm 5.000 104% 90-110 <br />CCB ppm -0.001 0.1 <br />CCV ppm 5.000 103% 90-110 <br />CCB ppm 0.001 0.1 <br />CCV ppm 5.000 93.8% 90-110 <br />CCB ppm 0.004 0.1 <br />Sodium 6010B 06/30/21:209986AC >131>0:1>CCI UUUUUU C-)C-WUUU ppm 25.00 102% 90-110 <br />ppm 0.16 1.0 <br />ppm 25.00 101% 90-110 <br />PPIrl 0.17 1.0 <br />ppm 25.00 93.5 % 90-110 <br />ppm 0.21 1.0 <br />Wet Chem <br />PH 4500HB 06/29/21:209912J8A CCV units 8.000 101 % 95-105 <br />CCV units 8.000 101 % 95-105 <br />9045C (STK2138791-001) Dup units 0.2% 5.84 <br />Definition <br />PDS : PDS failed, matrix - Post Diges ion Spike (PDS) not within Acceptance Range (AR) because of matrix interferences affecting this <br />analyte. Data was accepted based on the LCS recovery. <br />CCV : Continuing Calibration Verification - Analyzed to verify the instrument calibration is within criteria. <br />CCB : Continuing Calibration Blank - Analyzed to verify the instrument baseline is within criteria. <br />Blank : Method Blank - Prepared to verify that the preparation process is not contributing contamination to the samples. <br />LCS : Laboratory Control Standard/Sample - Prepared to verify that the preparation process is not affecting analyte recovery. <br />MS : Matrix Spikes - A random sample is spiked with a known amount of analyte. The recoveries are an indication of how that sample <br />matrix affects analyte recovery. <br />MSD : Matrix Spike Duplicate of MS/MSD pair - A random sample duplicate is spiked with a known amount of analyte. The recoveries <br />are an indication of how that sample matrix affects analyte recovery. <br />D up : Duplicate Sample - A random sample with each batch is prepared and analyzed in duplicate. The relative percent difference is an <br />indication of precision for the preparation and analysis. <br />MSRPD : MS/MSD Relative Percent Difference (RPD) - The MS relative percent difference is an indication of precision for the preparation <br />and analysis. <br />ND : Non-detect - Result was below the DQO listed for the analyte. <br />High Sample Background - Spike concentration was less than one forth of the sample concentration. <br />DQO : Data Quality Objective - This is the criteria against which the quality control data is compared. <br />Explanation <br />430 : Post Digestion Spike (PDS) not within Acceptance Range (AR) because of matrix interferences affecting this analyte. Data was <br />accepted based on the LCS recovery. <br />435 : Sample matrix may be affecting this analyte. Data was accepted based on the LCS or CCV recovery. <br />Page 9 of 9 <br />Corporate Offices & Laboratory <br />853 Corporation Street <br />Santa Paula, CA 93060 <br />TEL: (805)392-2000 <br />Env FAX: (805)525-4172 / Ag FAX: <br />CA ELAP Certification No. 1573 <br />Office & Laboratory <br />2500 Stagecoach Road <br />Stockton, CA 95215 <br />TEL: (209)942-0182 <br />(805)392-2063 FAX: (209)942-0423 <br />CA ELAP Certification No. 1563 <br />Office & Laboratory <br />563 E. Lind° Avenue <br />Chico, CA 95926 <br />TEL: (530)343-5818 <br />FAX: (530)343-3807 <br />CA ELAP Certification <br />Office & Laboratory <br />3442 Empresa Drive, Suite D <br />San Luis Obispo, CA 93401 <br />TEL: (805)783-2940 <br />FAX: (805)783-2912 <br />No. 2670 CA ELAP Certification No. 2775 <br />Office & Laboratory <br />9415W. Goshen Avenue <br />Visalia, CA 93291 <br />TEL: (559)734-9473 <br />FAX: (559)734-8435 <br />CA ELAP Certification No. 2810